Modeling and optimization of reactive extraction equilibria and kinetic study of gallic acid using tributyl phosphate in isoamyl alcohol

2020 ◽  
pp. 1-12 ◽  
Author(s):  
Nishant Joshi ◽  
Amit Keshav ◽  
A.K. Poonia
Keyword(s):  
Kinetic Study ◽  
Gallic Acid ◽  
Tributyl Phosphate ◽  
Isoamyl Alcohol ◽  
Reactive Extraction ◽  
Modeling And Optimization ◽  
Extraction Equilibria

Modeling and Optimization of Reactive Extraction of Gallic Acid Using RSM

2017 ◽  
Vol 204 (4) ◽  
pp. 522-528 ◽  
Author(s):  
Kalpana Rewatkar ◽  
Diwakar Z. Shende ◽  
Kailas L. Wasewar
Keyword(s):  
Gallic Acid ◽  
Reactive Extraction ◽  
Modeling And Optimization

scholarly journals REMOVAL OF TRIBUTYL PHOSPHATE FROM AQUEOUS SOLUTIONS BY TiO2 HETEROGENEOUS PHOTOCATALYSIS SUPPORTED OVER A NEW METAL PLATE WITH KINETIC STUDY

2019 ◽  
Vol 36 (2) ◽  
pp. 669-680 ◽  
Author(s):  
Otidene R. S. da Rocha ◽  
Joyce E. Oliveira ◽  
Luciano C. Almeida ◽  
Tulio D. da Silva ◽  
Josivan P. da Silva ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Kinetic Study ◽  
Tributyl Phosphate ◽  
Heterogeneous Photocatalysis ◽  
Metal Plate

scholarly journals Reactive Extraction of L (+) Tartaric Acid by Amberlite LA-2 in Different Solvents

2011 ◽  
Vol 8 (s1) ◽  
pp. S509-S515 ◽  
Author(s):  
I. Inci ◽  
Y. S. Asçi ◽  
A. F. Tuyun
Keyword(s):  
Tartaric Acid ◽  
Extraction Efficiency ◽  
Methyl Isobutyl Ketone ◽  
Distribution Coefficients ◽  
Reactive Extraction ◽  
Methyl Isobutyl ◽  
Isobutyl Ketone ◽  
Initial Concentration ◽  
Maximum Removal ◽  
Extraction Equilibria

The extraction of L(+) tartaric acid from aqueous solutions by amberlite LA-2 is a secondary amine mixture in different diluent solvents. Extraction equilibria of L(+) tartaric acid by amberlite LA-2 in 1-octanol, cyclohexane, isooctane, hexane, methyl isobutyl ketone (MIBK) solvents at temperature 298.15 K have been measured. The batch extraction experiments distribution coefficients (D), loading factors (Z) and extraction efficiency (E) were calculated. The maximum removal of L(+) tartaric acid is 91 % with MIBK and 0.92 mol.L-1initial concentration of Amberlite LA-2.

STUDIES ON THE URANIUM EXTRACTION EQUILIBRIA, PHOTOLYTIC, AND HYDROLYTIC REACTIONS IN SYSTEMS CONTAINING TRI-n-BUTOXYETHYL PHOSPHATE

1964 ◽  
Vol 42 (4) ◽  
pp. 878-884 ◽  
Author(s):  
M. Halpern ◽  
T. Kim ◽  
A. S. Kertes ◽  
N. C. Li
Keyword(s):  
Aqueous Solution ◽  
Hydrochloric Acid ◽  
Organic Phase ◽  
Acid Content ◽  
Tributyl Phosphate ◽  
Extraction Behavior ◽  
Initial Aqueous Solution ◽  
Hydrolysis Of ◽  
Ethereal Oxygen ◽  
Extraction Equilibria

The extraction equilibria in the system aqueous hydrochloric acid – uranyl chloride –undiluted tri-n-butoxyethyl phosphate, TBEP, were examined as a function of increasing uranyl concentration (0.44 to 4.41 M) in the initial aqueous solution, the acid content of the initial aqueous solution being kept constant at 6.76 M. The extraction behavior of TBEP is found to be different from that of tributyl phosphate. Evidence has been presented to show that the three ethereal oxygen atoms in the TBEP molecule are, under high organic phase loading conditions, available for participation in complexation. The hydrochloric acid promoted hydrolysis of TBEP and the instability toward light of the TBEP layer containing hydrochloric acid and uranium were also examined.

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