Potential of Canola Stalk as Biosorbent for the Removal of Remazol Black B Reactive Dye from Aqueous Solutions

2012 ◽  
Vol 32 (4) ◽  
pp. 328-341 ◽  
Author(s):  
Alireza Ashori ◽  
Yahya Hamzeh ◽  
Elham Azadeh ◽  
Soheila Izadyar ◽  
Mohammad Layeghi ◽  
...  
2011 ◽  
Vol 9 (5) ◽  
pp. 867-876 ◽  
Author(s):  
Monika Wawrzkiewicz ◽  
Zbigniew Hubicki

AbstractIn this study, the use of the weakly basic anion exchange resins of phenol-formaldehyde (Amberlyst A 23), polyacrylate (Amberlite IRA 67) and polystyrene (Lewatit MonoPlus MP 62) matrices for removal of the reactive dye Remazol Black B (RBB) from aqueous solution and wastewater were investigated. RBB sorption on the anion exchangers was a time dependent process. Color reduction percentiles of 75.2, 33.9 and 25.1% in wastewater treatment were found after 216 h of phase contact time with Lewatit MonoPlus MP 62, Amberlyst A 23 and Amberlite IRA 67, respectively. Inorganic salts and anionic surfactant action influenced RBB uptake by the anion exchangers. The amounts of dye retained by the anion exchangers increased with a rise in temperature. The maximum sorption capacities calculated from the Langmuir model were 66.4, 282.1 and 796.1 mg g−1 for Amberlite IRA 67, Amberlyst A 23 and Lewatit MonoPlus MP 62, respectively. Regeneration of phenol-formaldehyde and polystyrene resins were possible using 1 M NaOH, 2 M KSCN, 1M KSCN in 40–60% methanol as well as 1 M NaOH in 60% methanol.


2009 ◽  
Vol 163 (1) ◽  
pp. 187-198 ◽  
Author(s):  
Özlem Tunç ◽  
Hacer Tanacı ◽  
Zümriye Aksu

2019 ◽  
Vol 25 (4) ◽  
pp. 341-351
Author(s):  
Aleksandar Zdravkovic ◽  
Novica Stankovic ◽  
Nebojsa Ristic ◽  
Goran Petkovic

The aim of this study was to determine adsorptive properties of acid activated bentonite clay for the removal of Direct Red 173 (DR 173) and Reactive Red 22 (RR 22) dyes from aqueous solutions. Raw and modified clay were characterized by the following methods: Fourier transform infrared spectroscopy (FTIR), X-ray powder diffraction (XRPD), and scanning electron microscopy (SEM). The efficiency of activated clay adsorption was investigated depending on process parameters: the adsorbent dose, pH, temperature, initial dye concentration, and contact time. Experimental data were analyzed by Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich isotherm as well as kinetic models of pseudo-first order, pseudo-second order and intra-particle diffusion. The process of dye adsorption was best described by Langmuir, Temkin, and Dubinin-Radushkevich isotherm (R2 > 0.97). Pseudo-second order model (R2 > 0.99) had the highest correlation with the obtained kinetic results. The positive value of ?H? indicated that adsorption of dyes by activated bentonite clay is endothermic process. The activated bentonite exhibited good regenerative ability in the 0.1 M NaOH solution. Maximum adsorption capacities of acid activated bentonite clay at 25?C for DR 173 and RR 22 dyes were 356.65 and 109.58 ?mol g-1, respectively.


2019 ◽  
Vol 2019 ◽  
pp. 1-15 ◽  
Author(s):  
Pham Dinh Du ◽  
Huynh Thi Minh Thanh ◽  
Thuy Chau To ◽  
Ho Sy Thang ◽  
Mai Xuan Tinh ◽  
...  

In the present paper, the synthesis of metal-organic framework MIL-101 and its application in the photocatalytic degradation of Remazol Black B (RBB) dye have been demonstrated. The obtained samples were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS), and nitrogen adsorption/desorption isotherms at 77 K. It was found that MIL-101 synthesized under optimal conditions exhibited high crystallinity and specific surface area (3360 m2·g-1). The obtained MIL-101 possessed high stability in water for 14 days and several solvents (benzene, ethanol, and water at boiling temperature). Its catalytic activities were evaluated by measuring the degradation of RBB in an aqueous solution under UV radiation. The findings show that MIL-101 was a heterogeneous photocatalyst in the degradation reaction of RBB. The mechanism of photocatalysis was considered to be achieved by the electron transfer from photoexcited organic ligands to metallic clusters in MIL-101. The kinetics of photocatalytic degradation reaction were analyzed by using the initial rate method and Langmuir-Hinshelwood model. The MIL-101 photocatalyst exhibited excellent catalytic recyclability and stability and can be a potential catalyst for the treatment of organic pollutants in aqueous solutions.


2011 ◽  
Vol 7 (4) ◽  
pp. 286-295 ◽  
Author(s):  
Irfan Timur ◽  
B. Filiz Senkal ◽  
Nagihan M. Karaaslan ◽  
Tulin BAL ◽  
Emine Cengiz ◽  
...  

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