Ultraviolet Difference Spectral Studies in the Gamma Radiolysis of DNA and Model Compounds. I. Aqueous Solutions of DNA Bases

1989 ◽  
Vol 56 (6) ◽  
pp. 923-941 ◽  
Author(s):  
C.N. Trumbore ◽  
C.T. Hyde ◽  
R.D. Hudson ◽  
L.A. Jurman ◽  
A.G. Gehring ◽  
...  
2010 ◽  
Vol 184 (1-3) ◽  
pp. 308-312 ◽  
Author(s):  
Dongkyu Choi ◽  
O-Mi Lee ◽  
Seungho Yu ◽  
Seung-Woo Jeong

2011 ◽  
Vol 6 (9) ◽  
pp. 1934578X1100600
Author(s):  
Alejandro Valdez-Calderón ◽  
J. Martín Torres-Valencia ◽  
J. Jesús Manríquez-Torres ◽  
René Velázquez-Jiménez ◽  
Mario A. Gómez-Hurtado ◽  
...  

The new sesquiterpene (1 R,2 R,3 R,6 R,7 S)-1-acetoxy-2,3-dmydroxy-2,3-dihydrobisabolene (3) together with ten known terpenes and three known flavonoids were isolated from the aerial parts and from the roots of Stevia tomentosa. The structure of 3 follows from spectral studies, the relative chirality at C-3 follows from 1H NMR coupling constants comparison with the corresponding calculated values obtained by applying a generalized Karplus-type relationship to the dihedral angles of model compounds, and the absolute configuration is assumed in analogy to known (2 R,3 R,6 R,7 S)-2,3-epoxy-2,3-dihydrobisabolen-1-one (2).


1971 ◽  
Vol 49 (9) ◽  
pp. 1510-1514 ◽  
Author(s):  
M. H. Brooker ◽  
D. E. Irish

Infrared and Raman spectra are reported for the hexaquozinc nitrate crystal. Replacement of water by deuterium oxide causes a remarkable intensity reversal of components in the ν3 nitrate region and provides Raman spectra free from interference in the 2ν2 and ν4 regions. The nitrate spectrum is interpreted in terms of a site group approximation. The spectra are compared with those of concentrated aqueous solutions and partially dehydrated crystals to point up changes which result from a lowered site symmetry and those which result from ionic association.


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