The Effects of Weight Hour Space Velocity on the Products Distribution of Aromatization Reaction of Lanlian FCC Gasoline

2010 ◽  
Vol 28 (10) ◽  
pp. 1025-1035
Author(s):  
H. Lu ◽  
H. You
2018 ◽  
Vol 83 (4) ◽  
pp. 473-488 ◽  
Author(s):  
Abbas Roshanaei ◽  
Mehdi Alavi

The kinetic studies of propane aromatization reaction over Zn/ /HZSM-5 catalyst at temperature of 500?560?C and space velocity of 500?2500 cm3 gcat -1 h-1, in a plug flow reactor, under catalyst deactivating conditions were performed. A lumped kinetic model consisting of six lumped components and six reaction steps was proposed to describe the aromatization of propane. The kinetic model involves 18 kinetic parameters and one catalyst deactivation constant. The reaction steps orders were obtained by the power law model. Frequency factors and the apparent activation energies of the reaction steps were calculated based on the Arrhenius equation. An exponential function depending on the time-on-stream was applied for the catalyst deactivation model and the kinetic parameters were calculated via a genetic algorithm. The kinetic results indicated that the lumped kinetic model can well estimate the product yields of propane aromatization.


2006 ◽  
Vol 7 (8) ◽  
pp. 554-558 ◽  
Author(s):  
Hongjun You ◽  
Chunming Xu ◽  
Jinsen Gao ◽  
Zhichang Liu ◽  
Pinxiang Yan

2017 ◽  
Vol 68 (7) ◽  
pp. 1496-1500
Author(s):  
Rami Doukeh ◽  
Mihaela Bombos ◽  
Ancuta Trifoi ◽  
Minodora Pasare ◽  
Ionut Banu ◽  
...  

Hydrodesulphurization of dimethyldisulphide was performed on Ni-Co-Mo /�-Al2O3 catalyst. The catalyst was characterized by determining the adsorption isotherms, the pore size distribution and the acid strength. Experiments were carried out on a laboratory echipament in continuous system using a fixed bed catalytic reactor at 50-100�C, pressure from 10 barr to 50 barr, the liquid hourly space velocity from 1h-1 to 4h-1 and the molar ratio H2 / dimethyldisulphide 60/1. A simplified kinetic model based on the Langmuir�Hinshelwood theory, for the dimethyldisulphide hydrodesulfurization process of dimethyldisulphide has been proposed. The results show the good accuracy of the model.


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