Electrocatalysis of Inorganic Reactions: Pure Platinum Surfaces

Author(s):  
Thomas J. Schmidt ◽  
Nenad M. Markovic
ChemInform ◽  
2013 ◽  
Vol 44 (12) ◽  
pp. no-no
Author(s):  
Thomas J. Schmidt ◽  
Nenad M. Markovic

Author(s):  
R. L. Hines

The importance of atom layer terraces or steps on platinum surfaces used for catalysis as discussed by Somorjai justifies an extensive investigation of the structure of platinum surfaces through electron microscopy at the atomic resolution level. Experimental and theoretical difficulties complicate the quantitative determination of platinum surface structures but qualitative observation of surface structures on platinum crystals is now possible with good experimental facilities.Ultrathin platinum crystals with nominal 111 orientation are prepared using the procedure reported by Hines without the application of a carbon backing layer. Platinum films with thicknesses of about ten atom layers are strong enough so that they can be mounted on grids to provide ultrathin platinum crystals for examination of surface structure. Crystals as thin as possible are desired to minimize the theoretical difficulties in analyzing image contrast to determine structure. With the current preparation procedures the crystals frequently cover complete openings on a 400 mesh grid.


2019 ◽  
Vol 12 (1) ◽  
pp. 351-357 ◽  
Author(s):  
Yunchang Liang ◽  
David McLaughlin ◽  
Christoph Csoklich ◽  
Oliver Schneider ◽  
Aliaksandr S. Bandarenka

The recently introduced electrochemical scanning tunneling microscopy noise measurements were applied to directly identify active centers for oxygen electro-reduction at Pt-based surfaces in three alkaline electrolytes under reaction conditions.


2014 ◽  
Vol 16 (38) ◽  
pp. 20360-20376 ◽  
Author(s):  
Kun Jiang ◽  
Han-Xuan Zhang ◽  
Shouzhong Zou ◽  
Wen-Bin Cai

A brief overview is presented on recent progress in mechanistic studies of formic acid oxidation, synthesis of novel Pd- and Pt-based nanocatalysts and their practical applications in direct formic acid fuel cells.


2005 ◽  
Vol 109 (49) ◽  
pp. 23543-23549 ◽  
Author(s):  
Vladimir Komanicky ◽  
Andreas Menzel ◽  
Kee-Chul Chang ◽  
Hoydoo You

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