Dynamic Properties of Proton Transfer in the Anharmonic-Interaction Hydrogen Bond Systems

Temperature-dependent changes in the strong OHN hydrogen bond in 3-methylpyridinium 2,6-dichloro-4-nitrophenolate are used to discuss the proton transfer mechanism.

Download Full-text

Construction of the Model Strong Hydrogen Bond Potential Energy Surface and Proton Transfer Dynamics

NATO ASI Series - Proton Transfer in Hydrogen-Bonded Systems ◽

10.1007/978-1-4615-3444-0_4 ◽

1992 ◽

pp. 49-63

Author(s):

N. D. Sokolov ◽

M. V. Vener

Keyword(s):

Hydrogen Bond ◽

Potential Energy ◽

Proton Transfer ◽

Potential Energy Surface ◽

Energy Surface ◽

Strong Hydrogen Bond

Download Full-text

Hydrogen-Bond Circumstances and Dynamic Properties of Low-Temperature Pore Water, as Assessed from Thermal Behaviors

Nippon Shokuhin Kagaku Kogaku Kaishi ◽

10.3136/nskkk.65.132 ◽

2018 ◽

Vol 65 (3) ◽

pp. 132-141

Author(s):

Masaharu Oguni ◽

Atsushi Nagoe ◽

Hiroki Niwano ◽

Kiyoshi Kawai

Keyword(s):

Hydrogen Bond ◽

Low Temperature ◽

Pore Water ◽

Dynamic Properties ◽

Thermal Behaviors

Download Full-text

Crystal structure and hydrogen bonding in the water-stabilized proton-transfer salt brucinium 4-aminophenylarsonate tetrahydrate

Acta Crystallographica Section E Crystallographic Communications ◽

10.1107/s2056989016006691 ◽

2016 ◽

Vol 72 (5) ◽

pp. 751-755 ◽

Cited By ~ 1

Author(s):

Graham Smith ◽

Urs D. Wermuth

Keyword(s):

Crystal Structure ◽

Hydrogen Bond ◽

Hydrogen Bonding ◽

Hydrogen Bonds ◽

Proton Transfer ◽

Network Structure ◽

Three Dimensional ◽

Water Molecules ◽

Arsanilic Acid ◽

Dimensional Network

In the structure of the brucinium salt of 4-aminophenylarsonic acid (p-arsanilic acid), systematically 2,3-dimethoxy-10-oxostrychnidinium 4-aminophenylarsonate tetrahydrate, (C23H27N2O4)[As(C6H7N)O2(OH)]·4H2O, the brucinium cations form the characteristic undulating and overlapping head-to-tail layered brucine substructures packed along [010]. The arsanilate anions and the water molecules of solvation are accommodated between the layers and are linked to them through a primary cation N—H...O(anion) hydrogen bond, as well as through water O—H...O hydrogen bonds to brucinium and arsanilate ions as well as bridging water O-atom acceptors, giving an overall three-dimensional network structure.

Download Full-text