Influence of N–H–O hydrogen bonds on the structure and properties of (K1−x(NH4)xH2PO4) proton glasses: a single crystal neutron diffraction study

2013 ◽  
Vol 25 (7) ◽  
pp. 075902 ◽  
Author(s):  
Rajul Ranjan Choudhury ◽  
R Chitra
Keyword(s):  
Hydrogen Bonds ◽  
Neutron Diffraction ◽  
Single Crystal ◽  
Diffraction Study ◽  
Neutron Diffraction Study ◽  
Structure And Properties

Location of the proton in the very strong OHO hydrogen bonds in 2-(N,N-diethylamino-N-oxymethyl)-4,6-dichlorophenol. A single crystal neutron diffraction study

1997 ◽  
Vol 212 (2) ◽  
Author(s):  
H. Ptasiewicz-Bak ◽  
R. Tellgren ◽  
I. Olovsson ◽  
A. Koll
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Neutron Diffraction ◽  
Single Crystal ◽  
Diffraction Study ◽  
Neutron Diffraction Study ◽  
Crystallographic Symmetry ◽  
O 175.8 ◽  
Oxygen Atoms

AbstractThe crystal structure of 2-(N,N-diethylamino-N-oxymethyl)-4,6-dichlorophenol contains two slightly different molecules A and B, both with very strong intramolecular O … H … O hydrogen bonds, with O–O distances 2.423(4) Å and 2.400(5) Å, respectively, and with no crystallographic symmetry. The bridging oxygen atoms are also chemically different, O1 is bonded to carbon and O2 to nitrogen. The single crystal neutron diffraction study shows quite unambiguously that the proton in both cases is located slightly off-centred. In the A molecule O1–H = 1.167(6) Å, H–O2 = 1.258(6) Å and the angle O–H–O = 175.8(5)°; in the B molecule O1–H = 1.186(7) Å, H–O2 = 1.214(7) Å and the angle O–H–O = 176.5(5)°. As expected the proton is thus closer to the centre in the slightly shorter hydrogen bond.

scholarly journals H-bonding in lazulite: a single-crystal neutron diffraction study at 298 and 3 K

2018 ◽  
Vol 46 (5) ◽  
pp. 449-458
Author(s):  
G. Diego Gatta ◽  
Pietro Vignola ◽  
Nicola Rotiroti ◽  
Martin Meven
Keyword(s):  
Neutron Diffraction ◽  
Single Crystal ◽  
Diffraction Study ◽  
Neutron Diffraction Study

Minerals in cement chemistry: A single-crystal neutron diffraction study of ettringite, Ca6Al2(SO4)3(OH)12·27H2O

2019 ◽  
Vol 104 (1) ◽  
pp. 73-78 ◽  
Author(s):  
G. Diego Gatta ◽  
Ulf Hålenius ◽  
Ferdinando Bosi ◽  
Laura Cañadillas-Delgado ◽  
Maria Teresa Fernandez-Diaz
Keyword(s):  
Neutron Diffraction ◽  
Single Crystal ◽  
Diffraction Study ◽  
Neutron Diffraction Study

Single-crystal and powder neutron diffraction study of the Fe Mn1−S solid solutions

2015 ◽  
Vol 632 ◽  
pp. 563-567 ◽  
Author(s):  
Galina Abramova ◽  
Juerg Schefer ◽  
Nadir Aliouane ◽  
Martin Boehm ◽  
German Petrakovskiy ◽  
...  
Keyword(s):  
Neutron Diffraction ◽  
Single Crystal ◽  
Diffraction Study ◽  
Solid Solutions ◽  
Neutron Diffraction Study ◽  
Powder Neutron Diffraction
Sign in / Sign up

Export Citation Format

Share Document