scholarly journals Immersed Corrosion Properties of the Microarc Oxidation Coating on as-cast AZ91D Magnesium Alloy

Author(s):  
Y Lv ◽  
J G Li ◽  
M Z Wu ◽  
H Y Wang ◽  
D Q Zhang ◽  
...  
2009 ◽  
Vol 51 (12) ◽  
pp. 2950-2958 ◽  
Author(s):  
Xiankang Zhong ◽  
Qing Li ◽  
Bo Chen ◽  
Juping Wang ◽  
Junying Hu ◽  
...  

2014 ◽  
Vol 1004-1005 ◽  
pp. 733-736
Author(s):  
Zu Xiao Yu ◽  
Ya Li Sun ◽  
Xin Huang

To improve the anti-corrosion properties of the AZ91D magnesium alloy, the electroless plating Ni-Co-P on the AZ91D magnesium alloy is necessary. The influences of additives (ammonium fluoride (NH4F) and hexamethylenetetramine (HMTA)) on deposition rate, corrosion rate, acid resistance, corrosion current, corrosion potential and webster hardness of electroless plating Ni-Co-P alloy coating, were investigated using electrochemical methods, etc. The results show that the deposition rate and corrosion resistance properties of electroless plating Ni-Co-P are obviously improved when the additives, including NH4F (2%) and hexamethylenetetramine (HMTA, 1%), are added into plating solution, respectively. In addition, the global particles in the Ni-Co-P coating become smaller with the addition of NH4F by comparison with no additives and coatings are dense, uniform and defect-free.


2008 ◽  
Vol 50 (12) ◽  
pp. 3267-3273 ◽  
Author(s):  
He Meifeng ◽  
Liu Lei ◽  
Wu Yating ◽  
Tang Zhixin ◽  
Hu Wenbin

2013 ◽  
Vol 668 ◽  
pp. 779-783 ◽  
Author(s):  
Shu Yan Wang ◽  
Yong Ping Xia ◽  
Li Liu ◽  
Qiao Chen

Ceramic coatings were fabricated on AZ91D magnesium alloy in a novel optimized dual electrolyte by Microarc oxidation. The influence of duty cycle on coating thickness, surface roughness, phase composition, microstructure and corrosion resistance were studied. It is found that both the thickness and surface roughness of coatings increases gradually with the increasing of duty cycle. XRD results show that all the coatings are mainly composed of MgO, Mg2SiO4 and MgAl2O4. The results of potentiodynamic polarization tests indicate that the coating formed at 40% duty cycle exhibits a better corrosion resistance as a result of its relatively compact microstructure and more relative content of Mg2SiO4 and MgAl2O4 phases.


2009 ◽  
Vol 16 (06) ◽  
pp. 821-830 ◽  
Author(s):  
X. P. ZHANG ◽  
Y. S. ZOU ◽  
F. M. WU ◽  
Z. P. ZHAO ◽  
L. YOU ◽  
...  

The wear resistances of AZ91D magnesium alloy with and without microarc oxidation (MAO) coating and Ti 6 Al 4 V alloy in artificial saliva were investigated at room temperature. The wear resistance of AZ91D magnesium alloy in artificial saliva was significantly improved after microarc oxidation treatment. The volume loss of untreated AZ91D magnesium alloy sample was 20.95 times of that of AZ91D magnesium alloy with MAO coating, and that of Ti 6 Al 4 V was 5.42 times of that of MAO. Furthermore, the wear resistance of AZ91D magnesium alloy was lower than that of Ti 6 Al 4 V alloy in artificial saliva. The wear mechanisms of AZ91D magnesium and Ti 6 Al 4 V were discussed. It was found that the wear mechanism of the MAO was associated with abrasion and microfracture. There were two dominative wear mechanisms for AZ91D alloy and Ti 6 Al 4 V alloy under the loading conditions used in the experiment, namely, micro-machining wear and deformation-induced wear.


2012 ◽  
Vol 502 ◽  
pp. 320-324 ◽  
Author(s):  
Shu Yan Wang ◽  
Yong Ping Xia ◽  
Li Liu

Microarc oxidation (MAO) coatings were prepared on AZ91D magnesium alloy in a novel dual electrolyte containing various concentrations of sodium citrate (C6H5Na3O7). The surface and cross-sectional morphologies, coating thickness and surface roughness were characterized by scanning electron microscopy (SEM), layer thickness meter and digital microscope, respectively. The corrosion resistance of coatings was evaluated by electrochemical impedance spectroscopy (EIS). The results showed that both the striking voltage and final voltage decreased gradually with the increase of C6H5Na3O7 concentration. When the C6H5Na3O7 concentration increased, surface roughness increased gradually, while thickness of the coating increased at first and then decreased. The coating formed in the electrolyte containing 5g/L C6H5Na3O7 had a much more uniform and compact microstructure with less micropores and micro-cracks. EIS test showed that the concentration of C6H5Na3O7 mainly affected the corrosion resistance of inner dense layer, and the coating with best corrosion resistance was obtained in the electrolyte containing 5g/L C6H5Na3O7.


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