scholarly journals Amyand David Buckingham. 28 January 1930—4 February 2021

Author(s):  
David C. Clary ◽  
Brian J. Orr

David Buckingham was a chemical physicist and theoretical chemist who made fundamental contributions to the understanding of optical, electric and magnetic properties of molecules. Born in Australia, he was an undergraduate at the University of Sydney and the first PhD research student of John Pople (FRS 1961) at Cambridge, and there he made significant advances in the theory of intermolecular forces and nonlinear optics. He then moved to Oxford, where he and his group performed the first direct measurement of a molecular electric quadrupole moment. He was elected to the first chair of theoretical chemistry at the University of Bristol, where he wrote a particularly influential article on molecular moments, higher-order polarizabilities and intermolecular forces. His next appointment was at the University of Cambridge as the first holder of the 1968 Chair of Chemistry, and he was head of a distinguished department of theoretical chemistry for 28 years. With colleagues he pioneered experiment and theory on vibrational optical activity and developed a powerful model to predict the structures of weakly-bound molecules. A man of broad interests and achievements, he played first class cricket in the 1950s.

1999 ◽  
Vol 451 (1-2) ◽  
pp. 11-18 ◽  
Author(s):  
H. Ogawa ◽  
K. Asahi ◽  
K. Sakai ◽  
A. Yoshimi ◽  
M. Tsuda ◽  
...  

1970 ◽  
Vol 31 (8) ◽  
pp. 520-522 ◽  
Author(s):  
K. Sugimoto ◽  
A. Mizobuchi ◽  
K. Matuda ◽  
T. Minamisono

1999 ◽  
Vol 304 (5-6) ◽  
pp. 414-422 ◽  
Author(s):  
Vladimir Kellö ◽  
Andrzej J. Sadlej ◽  
Pekka Pyykkö ◽  
Dage Sundholm ◽  
Maria Tokman

1982 ◽  
Vol 37 (10) ◽  
pp. 1165-1175 ◽  
Author(s):  
W. H. Stolze ◽  
M. Stolze ◽  
D. Hübner ◽  
D. H. Sutter

The rotational Zeeman effect in fluorobenzene is reinvestigated with a resolution improved by a factor of almost five to give more accurate g-tensor elements, magnetic susceptibility anisotropics and molecular electric quadrupole moments. The results fit into the pictures of a linear dependence of the out of plane molecular electric quadrupole moment, Qcc, on the number of fluorine substituents and of a linear correlation between the nonlocal (ring current) susceptibility, Χccnonlocal, and the CNDO/2-π-electron density alternation. They lead to a gasphase molecular electric quadrupole moment in benzene, Qcc,benzene = - (28.4 ± 4.7) · 10-40 Cm2 which is slightly less negative than the value deduced from electric field-gradient birefringence experiments on dilute benzene solutions with carbon tetrachloride as solvent. A detailed description of the high resolution microwave spectrometer is given in the appendix.


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