Perturbation Theory with Sommerfeld-Maue Wave Function

1954 ◽  
Vol 94 (5) ◽  
pp. 1402-1403 ◽  
Author(s):  
G. K. Horton ◽  
E. Phibbs
Open Physics ◽  
2016 ◽  
Vol 14 (1) ◽  
pp. 492-497
Author(s):  
Biswanath Rath ◽  
P. Mallick

AbstractWe present a complete energy and wavefunction analysis of a Harmonic oscillator with simultaneous non-hermitian transformations of co-ordinate $(x \rightarrow \frac{(x + i\lambda p)}{\sqrt{(1+\beta \lambda)}})$ and momentum $(p \rightarrow \frac {(p+i\beta x)}{\sqrt{(1+\beta \lambda)}})$ using perturbation theory under iso-spectral conditions. We observe that two different frequencies of oscillation (w1, w2)correspond to the same energy eigenvalue, - which can also be verified using a Lie algebraic approach.


As a preliminary to a wide range of applications, conventional perturbation theory is re-examined and a number of useful properties emphasized. It is shown in particular that the total, kinetic and potential energies can be obtained to the (2 s + 1)th order from a knowledge of only the s th-order wave function and that similar though less powerful theorems hold for other diagonal matrix elements. A combination of variational and perturbation techniques is suggested as the best method of calculating small disturbances of a stationary system.


1936 ◽  
Vol 32 (2) ◽  
pp. 260-264 ◽  
Author(s):  
C. E. Easthope

1. The problem of calculating the polarizability of molecular hydrogen has recently been considered by a number of investigators. Steensholt and Hirschfelder use the variational method developed by Hylleras and Hassé. For ψ0, the wave function of the unperturbed molecule when no external field is present, they take either the Rosent or the Wang wave function, while the wave functions of the perturbed molecule were considered in both the one-parameter form, ψ0 [1+A(q1 + q2)] and the two-parameter form, ψ0 [1+A(q1 + q2) + B(r1q1 + r2q2)], where A and B are parameters to be varied so as to give the system a minimum energy, q1 and q2 are the coordinates of the electrons 1 and 2 in the direction of the applied field as measured from the centre of the molecule, and r1 and r2 are their respective distances from the same point. Mrowka, on the other hand, employs a method based on the usual perturbation theory. Their numerical results are given in the following table.


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