Theoretical study of collision-induced far-infrared absorption of dense rare-gas mixtures

1982 ◽  
Vol 25 (2) ◽  
pp. 773-781 ◽  
Author(s):  
B. Guillot ◽  
S. Bratos ◽  
G. Birnbaum
1965 ◽  
Vol 43 (5) ◽  
pp. 729-750 ◽  
Author(s):  
D. R. Bosomworth ◽  
H. P. Gush

A study is being made of the far infrared absorption occurring in compressed rare-gas mixtures, and compressed homonuclear diatomic gases. The region investigated lies between 20 and 400 cm−1. The spectra are obtained from the Fourier analysis of interferograms produced by a dynamic Michelson interferometer. It is possible to obtain accurate absolute absorption coefficients for broad bands using this method provided care is exercised in the analysis of the interferograms. The necessary precautions are discussed in detail. The precision of the method obtained in practice is demonstrated using the far infrared bands of hydrogen and nitrogen as examples. Only the experimental techniques are discussed in this paper; the detailed results follow in a separate paper.


1976 ◽  
Vol 16 (6) ◽  
pp. 491-498 ◽  
Author(s):  
J. Quazza ◽  
Ph. Marteau ◽  
H. Vu ◽  
B. Vodar

1988 ◽  
Vol 65 (4) ◽  
pp. 765-784 ◽  
Author(s):  
B. Guillot ◽  
Ph. Marteau ◽  
J. Obriot

1986 ◽  
Vol 90 (23) ◽  
pp. 6154-6158 ◽  
Author(s):  
Conrad Naleway ◽  
Mitio Inokuti ◽  
Myran C. Sauer ◽  
Ronald Cooper

1973 ◽  
Vol 51 (18) ◽  
pp. 1971-1977 ◽  
Author(s):  
J. W. Mactaggart ◽  
J. De Remigis ◽  
H. L. Welsh

The profiles of the quadrupole-induced transitions (S1(0), S1(1)) of the pressure-induced fundamental infrared absorption band of hydrogen are studied in H2–Ar, H2–Kr, and H2–Xe gas mixtures up to high densities a few degrees above the critical temperature of the rare gas and in the corresponding liquid mixtures along the liquid–vapor line. The half-width δq of the transitions remains practically constant for the gas mixtures up to densities of several hundred amagat and then decreases rapidly. Values of δq for the liquid mixtures, when corrected for the temperature difference, are the same as the gas values at the same density. The narrowing of the transitions in the high-density region is interpreted in terms of the diffusional narrowing theory of Zaidi and Van Kranendonk, and is used to calculate diffusion coefficients D12 of H2 molecules in dense rare gas fluids. The results are in reasonable agreement with values of D12 previously deduced from the intercollisional interference effect in the overlap-induced components (Q1(0), Q1(1)) of the same band.


2014 ◽  
Vol 140 (15) ◽  
pp. 154302 ◽  
Author(s):  
Ilya Buryak ◽  
Lothar Frommhold ◽  
Andrey A. Vigasin

1965 ◽  
Vol 43 (5) ◽  
pp. 751-769 ◽  
Author(s):  
D. R. Bosomworth ◽  
H. P. Gush

The induced spectra of compressed helium–argon and neon–argon mixtures, and of compressed hydrogen, nitrogen, and oxygen have been measured in the frequency region 20 to 400 cm−1. The far-infrared spectra consist of a translational branch and a rotational branch which overlap, except in the rare-gas mixtures where only the translational component exists. The latter is a broad band which extends from zero frequency to about 500 cm−1, with a maximum near 150 cm−1 in the room-temperature gas. In the case of hydrogen the translational branch is readily distinguished from the rotational branch because it lies at a lower frequency than the latter. In the case of oxygen and nitrogen the spacing between the rotational lines is small and the translational and rotational branches overlap completely.


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