Nonrelativistic Wentzel-Kramers-Brillouin eigenvalues of the Thomas-Fermi neutral-atom potential in the large-atomic-number limit

1985 ◽  
Vol 32 (3) ◽  
pp. 1322-1327 ◽  
Author(s):  
G. Senatore ◽  
N. H. March
2013 ◽  
Vol 27 (24) ◽  
pp. 1350178 ◽  
Author(s):  
GABRIEL GIL ◽  
AUGUSTO GONZALEZ

We study atoms with N electrons, and nuclear charge Z. It is well known that the cationic regime, Z > N, is qualitatively described by Thomas–Fermi theory. The anionic regime, Z < N, on the other hand, is characterized by an instability threshold at Zc ≲ N-1, below which the atom spontaneously emits an electron. We compute the slope of the energy curve at Z = N - 1 by means of a simple model that depends on the electron affinity and the covalent radius of the neutral atom with N - 1 electrons. This slope is used in order to estimate Zc, which is compared with previous numerical results. Extrapolation of the linear behavior in the opposite direction, up to Z = N, allows us to estimate the ionization potential of the atom with N electrons. The fact that the obtained ionization potentials are qualitatively correct is an indication that, with regard to certain properties, neutral atoms are closer to the anionic instability threshold than they are to the Thomas–Fermi, large Z, region. A regularized series is written for the ionization potential that fits both, the large Z and Z → Zc limits.


1967 ◽  
Vol 47 (3) ◽  
pp. 1029-1035 ◽  
Author(s):  
J. J. Gilvarry ◽  
R. E. Hartle ◽  
N. H. March
Keyword(s):  

1962 ◽  
Vol 17 (11) ◽  
pp. 728-731
Author(s):  
M. L. De

Defects of the electron scattering formula based on Thomas-Fermi atom model and of Lei segang's formula, are first briefly discussed in relation to image contrast problem in Electron Microscopy. A few aspects of the electron scattering formula of Lenz are then considered particularly for dealing with elements of low atomic number. From a consideration of this formula it is shown that the image contrast of a given mass thickness of object is liable to be dependent on the atomic number of the object.


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