Publisher's Note: Level shifts of rubidium Rydberg states due to binary interactions [Phys. Rev. A75, 032712 (2007)]

2007 ◽  
Vol 75 (3) ◽  
Author(s):  
A. Reinhard ◽  
T. Cubel Liebisch ◽  
B. Knuffman ◽  
G. Raithel
Keyword(s):  

Hydrogen atoms in Rydberg states (principal quantum number n ≫ 1) inserted between parallel mirrors separated by a distance L suffer level shifts now becoming measurable. The analysis in the preceding paper is applied to predict these shifts ⊿. When L < n 3 a /α ( a is the Bohr radius; α = e 2 / ħc ≈ 1/137), ⊿ is basically electrostatic (‘non-retarded’), and of order ( n / 4 / L 3 mm ) x 10 ‒6 Hz (with L expressed in millimetres). When L > n 3 a /α, ⊿ is basically radiative (‘retarded’), and of order (2/ n 2 L mm x 10 4 Hz. Fine structure and hyperfine structure are taken into account, considering the extreme cases of low orbital angular momenta ( l = 0, 1), and, more briefly, very high l (with ( n — l )/ n = O (1/ n )). Explicit formulae are given in the non-retarded régime, except for very small L , where ⊿ becomes comparable with the fine structure. In the retarded régime for low l , the requisite radial integrals are not available accurately, and only rough predictions can be made.


1992 ◽  
Vol 70 (2-3) ◽  
pp. 187-190 ◽  
Author(s):  
R. A. Swainson ◽  
G. W. F. Drake

The energy level shifts for an electron in a high-nL Rydberg state of an atom such as helium are well described by an asymptotic potential with terms proportional to the multipole moments of the core. We obtain exact analytic expressions as a function of n and L for second-order perturbation corrections to the energy due to the asymptotic potential. The results are of importance in the analysis of high-precision variational calculations and experimental transition energies for Rydberg states.


2007 ◽  
Vol 75 (3) ◽  
Author(s):  
A. Reinhard ◽  
T. Cubel Liebisch ◽  
B. Knuffman ◽  
G. Raithel
Keyword(s):  

2000 ◽  
Vol 98 (12) ◽  
pp. 793-806 ◽  
Author(s):  
Ian C. Lane, Andrew J. Orr-Ewing
Keyword(s):  

1991 ◽  
Vol 1 (8) ◽  
pp. 875-897 ◽  
Author(s):  
P. F. Brevet ◽  
Ch. Bordas ◽  
M. Broyer ◽  
G. Jalbert ◽  
P. Labastie

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