scholarly journals Piezomagnetism as a counterpart of the magnetovolume effect in magnetically frustrated Mn-based antiperovskite nitrides

2017 ◽  
Vol 96 (2) ◽  
Author(s):  
J. Zemen ◽  
Z. Gercsi ◽  
K. G. Sandeman
Keyword(s):  

2021 ◽  
Vol 6 (1) ◽  
Author(s):  
Yongqiang Qiao ◽  
Yuzhu Song ◽  
Andrea Sanson ◽  
Longlong Fan ◽  
Qiang Sun ◽  
...  

AbstractNegative thermal expansion (NTE) is an intriguing property, which is generally triggered by a single NTE mechanism. In this work, an enhanced NTE (αv = −32.9 × 10−6 K−1, ΔT = 175 K) is achieved in YbMn2Ge2 intermetallic compound to be caused by a dual effect of magnetism and valence transition. In YbMn2Ge2, the Mn sublattice that forms the antiferromagnetic structure induces the magnetovolume effect, which contributes to the NTE below the Néel temperature (525 K). Concomitantly, the valence state of Yb increases from 2.40 to 2.82 in the temperature range of 300–700 K, which simultaneously causes the contraction of the unit cell volume due to smaller volume of Yb3+ than that of Yb2+. As a result, such combined effect gives rise to an enhanced NTE. The present study not only sheds light on the peculiar NTE mechanism of YbMn2Ge2, but also indicates the dual effect as a possible promising method to produce enhanced NTE materials.



1986 ◽  
Vol 16 (8) ◽  
pp. 1107-1117 ◽  
Author(s):  
S Ishio ◽  
K Nushiro ◽  
M Takahashi
Keyword(s):  


2003 ◽  
Vol 72 (5) ◽  
pp. 1184-1190 ◽  
Author(s):  
Ikuo Nakai ◽  
Hatsuo Tange ◽  
Kensuke Konishi ◽  
Tatsuo Kamimori ◽  
Akifumi Chikazawa ◽  
...  


1995 ◽  
Vol 51 (18) ◽  
pp. 12410-12417 ◽  
Author(s):  
A. Z. Solontsov ◽  
D. Wagner


2007 ◽  
Vol 75 (17) ◽  
Author(s):  
J. L. Wang ◽  
S. J. Campbell ◽  
O. Tegus ◽  
C. Marquina ◽  
M. R. Ibarra


MRS Advances ◽  
2017 ◽  
Vol 2 (56) ◽  
pp. 3447-3452
Author(s):  
L. Bessais ◽  
M. Phejar ◽  
V. Paul-Boncour

ABSTRACTLaFe13−xSix compounds display a giant magnetocaloric effect near 200 K. The insertion of light elements (H, C) is used to improve the Curie temperature near ambient temperature for magnetic refrigeration applications. We have developed a synthesis method with a short annealing treatment compared to classical melting techniques. The parent intermetallic alloys were synthesized by high energy ball milling. The insertion of H atoms was carried out using a Sievert apparatus and the carbon atom was inserted by solid/solid reaction. Moreover, structural and magnetic results were carried out by neutron diffraction and Mössbauer spectrometry for H content (y = 0.7,1.5) and C content (y = 0.7). The cell parameter and the Fe magnetic moments versus temperature are determined. The misunderstanding on interstitial site is clarified. The magnetovolume effect on the Curie temperature is explained by combination of the structural and magnetic properties. The advantages and drawbacks of each type of element insertion are discussed.



1997 ◽  
Vol 259 (1-2) ◽  
pp. L1-L4 ◽  
Author(s):  
T. Kanomata ◽  
Y. Ise ◽  
N. Kumagai ◽  
A. Haga ◽  
K. Kamishima ◽  
...  
Keyword(s):  




2001 ◽  
Vol 226-230 ◽  
pp. 999-1001 ◽  
Author(s):  
C Marquina ◽  
M.R Ibarra ◽  
A.I Abramovich ◽  
A.V Michurin ◽  
L.I Koroleva


1980 ◽  
Vol 49 (5) ◽  
pp. 1790-1798 ◽  
Author(s):  
Yoshiro Kakehashi


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