scholarly journals QUANTITATIVE ABSORPTION SPECTRA OF THE COMMON CAROTENOIDS

1934 ◽  
Vol 9 (3) ◽  
pp. 693-694 ◽  
Author(s):  
Elmer S. Miller
2012 ◽  
Vol 100 (11) ◽  
pp. 112101 ◽  
Author(s):  
Masahiro Yoshita ◽  
Takayuki Okada ◽  
Hidefumi Akiyama ◽  
Makoto Okano ◽  
Toshiyuki Ihara ◽  
...  

1981 ◽  
Vol 36 (5-6) ◽  
pp. 431-439 ◽  
Author(s):  
Thomas Brandlmeier ◽  
Hugo Scheer ◽  
Wolfhart Rüdiger

Abstract Quantitative absorption spectra in the visible and UV region were recorded for denaturated phytochrome (P r) and phytochromobilin peptides in comparison with native Pr. The method was tested with C-phycocyanin from Spirulina platensis. Based on known molar absorptivities for denaturated phycocyanin and suitable model compounds, and on the ratio A620native/A655-665degraded = 2.9, ^native was determined to be 102000 m-1 cm-1 for one phycocyanobilin chromophore in native phycocyanin. Likewise, Native was calculated to be 19000 M-1 cm-1. The corresponding ratios for Pr were Anative/Adenatured = 3.4 and Anative/Adegraded = 3.7, this yielded ε665native = 109000 to 118000 and ε380native = 36000 M-1 cm-1 for phytochromobilin in native P r. This value corresponds to one phytochromobilin per small phytochrome (60000 D) if data from the literature are corrected for the content of colorless proteins. The latter has been asessed from (i) the purity index (A280/A665) and (ii) the contribution of the phytochromobilin chromophore at 280 nm as derived from model compounds.


1970 ◽  
Vol 25 (10) ◽  
pp. 1137-1143 ◽  
Author(s):  
Valentin Zanker ◽  
Ernst Rudolph ◽  
Gerhart Prell

Quantitative singlet absorption spectra dependent on solvent, temperature, and concentration are shown. The bands observed in the visible and UV region are assigned to 3 π → π*-electron transfers.Measurements at different acidities showed that the pheophytin molecule can be present in 3 prototropic forms; as a base, a mono- or a divalent cation.In polar solvents of concentrations >10-4 M dimerization occurred. Larger clusters were formed in non-polar solvents at concentrations <10-4 Μ and at temperatures below ca. 200 °K.The quantitative triplet (T) -absorption spectra for pheophytin a and b are also reported: the longest wavelength T-T-band is expected in the region 5000-8000 cm-1. The relaxation times and quantum yields of triplet formation are given; simple first order kinetics were found to fit the decay curves.


1978 ◽  
Vol 60 (1) ◽  
pp. 112-116 ◽  
Author(s):  
Joseph C. Roark ◽  
Richard A. Palmer ◽  
James S. Hutchison

1978 ◽  
Vol 48 ◽  
pp. 389-390 ◽  
Author(s):  
Chr. de Vegt

AbstractReduction techniques as applied to astrometric data material tend to split up traditionally into at least two different classes according to the observational technique used, namely transit circle observations and photographic observations. Although it is not realized fully in practice at present, the application of a blockadjustment technique for all kind of catalogue reductions is suggested. The term blockadjustment shall denote in this context the common adjustment of the principal unknowns which are the positions, proper motions and certain reduction parameters modelling the systematic properties of the observational process. Especially for old epoch catalogue data we frequently meet the situation that no independent detailed information on the telescope properties and other instrumental parameters, describing for example the measuring process, is available from special calibration observations or measurements; therefore the adjustment process should be highly self-calibrating, that means: all necessary information has to be extracted from the catalogue data themselves. Successful applications of this concept have been made already in the field of aerial photogrammetry.


1988 ◽  
Vol 102 ◽  
pp. 243-246
Author(s):  
J.T. Costello ◽  
W.G. Lynam ◽  
P.K. Carroll

AbstractThe dual laser-produced plasma technique for the study of ionic absorption spectra has been developed by the use of two Q-switched ruby lasers to enable independent generation of the absorbing and back-lighting plasmas. Optical pulse handling is used in the coupling cicuits to enable reproducible pulse delays from 250 nsec. to 10 msec, to be achieved. At delay times &gt; 700 nsec. spectra of essentially pure neutral species are observed. The technique is valuable, not only for obtaining the neutral spectra of highly refractory and/or corrosive materials but also for studying behaviour of ionic species as a function of time. Typical spectra are shown in Fig. 1.


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