A one-dimensionalABX3-type coordination polymer:catena-poly[benzyltrimethylammonium [tri-μ-chlorido-cadmium(II)]]
2013 ◽
Vol 69
(5)
◽
pp. 491-493
◽
Keyword(s):
The crystal structure of the title novel one-dimensionalABX3-type organic–inorganic hybrid complex {(C10H16N)[CdCl3]}n, (I), consists of benzyltrimethylammonium (Me3BzN+) cations and one-dimensional anionic {[Cd(μ-Cl)3]−}∞chains. Each CdIIcentre is hexacoordinated by bridging chloride ligands, giving a slightly distorted octahedral Cd(μ-Cl)6arrangement. The octahedra are linked by two opposite shared faces, giving rise to an almost perfectly linear anionic {[Cd(μ-Cl)3]−}∞chain in thea-axis direction. Me3BzN+cations located in the inter-chain spaces balance the charge. Noncovalent static attracting forces (Coulombic and van der Waals forces) and nonclassical C—H...Cl hydrogen-bond interactions stabilize the crystal structure.
2006 ◽
Vol 62
(7)
◽
pp. o2920-o2921
◽
Keyword(s):
2015 ◽
Vol 71
(1)
◽
pp. m3-m4
2013 ◽
Vol 69
(11)
◽
pp. m590-m590
2015 ◽
Vol 71
(10)
◽
pp. 1242-1244
Keyword(s):
2015 ◽
Vol 71
(6)
◽
pp. 423-429
◽
2012 ◽
Vol 68
(8)
◽
pp. m1055-m1055
◽
2015 ◽
Vol 71
(10)
◽
pp. o792-o793
Keyword(s):
2019 ◽
Vol 75
(6)
◽
pp. 880-887
◽
2007 ◽
Vol 63
(11)
◽
pp. i185-i185
◽
2012 ◽
Vol 68
(6)
◽
pp. o1884-o1884
◽
Keyword(s):