The effect of exchange coupling on the spectra of transition metal ions. The crystal structure and optical spectrum of CsCrBr3

1973 ◽  
Vol 29 (7) ◽  
pp. 1529-1532 ◽  
Author(s):  
T.-I. Li ◽  
G. D. Stucky
Keyword(s):  
Crystal Structure ◽  
Transition Metal ◽  
Metal Ions ◽  
Exchange Coupling ◽  
Optical Spectrum ◽  
Transition Metal Ions

Exchange Coupling of Transition-Metal Ions through Hydrogen Bonding:  A Theoretical Investigation

2002 ◽  
Vol 124 (18) ◽  
pp. 5197-5205 ◽  
Author(s):  
Cédric Desplanches ◽  
Eliseo Ruiz ◽  
Antonio Rodríguez-Fortea ◽  
Santiago Alvarez
Keyword(s):  
Hydrogen Bonding ◽  
Transition Metal ◽  
Metal Ions ◽  
Theoretical Investigation ◽  
Exchange Coupling ◽  
Transition Metal Ions

The crystal chemistry of (Mn3 +, Fe3+)-substituted andalusites (viridines and kanonaite), (Al1−x−yMn3x+Fe3y+)2 (OǀSiO4): crystal structure refinements, Mössbauer, and polarized optical absorption spectra

1981 ◽  
Vol 155 (1-2) ◽  
Author(s):  
I. Abs-Wurmbach ◽  
K. Langer ◽  
F. Seifert ◽  
E. Tillmanns
Keyword(s):  
Crystal Structure ◽  
Transition Metal ◽  
Optical Absorption ◽  
Metal Ions ◽  
Crystal Chemistry ◽  
Mixed Crystal ◽  
Transition Metal Ions ◽  
Structure Type ◽  
Optical Absorption Spectra ◽  
Distorted Octahedral

AbstractThe crystal chemistry of viridines and kanonaite, (AlThe structure refinements reveal that the transition metal ions substitute for Al almost exclusively in the distorted octahedral Al(l) site of the andalusite structure type within the entire mixed crystal series. This is independently proven by the Mössbauer results for

scholarly journals Dithiacrown Ether Substituted Porphyrazines:  Synthesis, Single-Crystal Structure, and Control of Aggregation in Solution by Complexation of Transition-Metal Ions

1996 ◽  
Vol 35 (4) ◽  
pp. 959-969 ◽  
Author(s):  
Cornelus F. van Nostrum ◽  
Franciscus B. G. Benneker ◽  
Hugo Brussaard ◽  
Huub Kooijman ◽  
Nora Veldman ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Transition Metal ◽  
Metal Ions ◽  
Single Crystal ◽  
Transition Metal Ions ◽  
Single Crystal Structure ◽  
And Control

Crystal-Structure of Bis(2,2'-6',2'-terpyridine)manganese(II) Bis(triiodide) [Mn(terpy)2](I3)2

1991 ◽  
Vol 44 (2) ◽  
pp. 303 ◽  
Author(s):  
R Bhula ◽  
DC Weatherburn
Keyword(s):  
Crystal Structure ◽  
Transition Metal ◽  
Metal Ions ◽  
Coordination Sphere ◽  
Metal Ion ◽  
Transition Metal Ions ◽  
Triclinic Space Group ◽  
X Ray ◽  
X Ray Crystallography ◽  
Distorted Octahedral

The crystal structure of [ Mn ( terpy )2](I3)2( terpy = 2,2°:6°,2°-terpyridene) has been determined by X-ray crystallography. The crystals are triclinic, space group Pī , a 9.357(4), b 8.600(2), c 24.531(8) Ǻ, α 93.64(2), B 95.58(3), γ 91.52(2)°, Z 2, V 1960(1)Ǻ3. The structure has been refined to a residual R of 0.065 (Rw 0.070). The coordination sphere of the metal ion is distorted octahedral with each terpy ligand coordinated in a meridional fashion. The structure is compared with those of other M( terpy )2n+ complexes formed by first-row transition metal ions.

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