Poly[[[(2,2′-bipyridine-κ2 N,N′)cobalt(II)]-μ3-5-hydroxyisophthalato-κ4 O,O′:O′′:O′′′] dihydrate]

2006 ◽  
Vol 62 (7) ◽  
pp. m1722-m1724 ◽  
Author(s):  
Xin Zhuo ◽  
Zhao-Rui Pan ◽  
Zuo-Wei Wang ◽  
Yi-Zhi Li ◽  
He-Gen Zheng
Keyword(s):  
Three Dimensional ◽  
Distorted Octahedral Geometry ◽  
Zigzag Chain ◽  
Two Dimensional ◽  
Bipy Ligand ◽  
One Dimensional ◽  
Hydrogen Bonding Interactions ◽  
Dimensional Network ◽  
Distorted Octahedral ◽  
The One

In the title compound, {[Co(C8H4O5)(C10H8N2)]·2H2O]} n or {[Co(OH-BDC)(2,2′-bipy)]·2H2O]} n (where OH-H2BDC is 5-hydroxyisophthalic acid and 2,2′-bipy is 2,2′-bipyridine), the Co atoms are chelated by two N atoms from the 2,2′-bipy ligand and by four O atoms from OH-BDC ligands in a highly distorted octahedral geometry. OH-BDC acts as a tetradentate ligand, with one carboxylate group chelating one Co atom and the other binding in a monodentate fashion to two other Co atoms to form a one-dimensional zigzag chain. In the crystal structure, one of the solvent water molecules lies on a crystallographic twofold axis. The one-dimensional molecular chains are assembled into a two-dimensional network via O—H...O hydrogen-bonding interactions, while π–π stacking interactions generate a three-dimensional open framework between the two-dimensional networks.

Formation of Nickel(II) Coordination Polymers by a Double Betaine: [{Ni(L)(H2O) 2} n] Cl2n.2nH2O and [{Ni(L)2(H2O)2} n

1997 ◽  
Vol 50 (1) ◽  
pp. 85 ◽  
Author(s):  
Ping-Rong Wei ◽  
De-Dong Wu ◽  
Bo-Mu Wu ◽  
Thomas C. W. Mak
Keyword(s):  
Layer Structure ◽  
Three Dimensional ◽  
Distorted Octahedral Geometry ◽  
Zigzag Chain ◽  
X Ray Crystallography ◽  
Metal Atoms ◽  
Dimensional Network ◽  
Distorted Octahedral ◽  
Network Complex ◽  
Double Betaine

Two novel polymeric nickel(II) complexes of a double betaine with a rigidtris(ethylene) bridge between the pair of nitrogen atoms, namely [ {Ni(L)(H2O)4 }n]Cl2n.2nH2O(1)and [ {Ni(L)2(H2O)2} n](ClO4)2n.4nH2O(2) [L =¯O2CCH2N+(CH2CH2)3N+CH2CO2¯], have been prepared and characterized by X-ray crystallography. Thenickel(II) atom in either complex is coordinated by unidentate carboxylategroups and aqua ligands in a distorted octahedral geometry. The crystalstructure of (1) features an infinite zigzag chain composed of an alternatearrangement of metal atoms and double betaine ligands, and hydrogen bondingamong adjacent chains leads to a three-dimensional network. Complex (2)exhibits a wave-like layer structure corresponding to the (2 0 0) family ofplanes.

A two-dimensional cadmium(II) coordination polymer based on 1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane and thiocyanate ligands

2015 ◽  
Vol 71 (9) ◽  
pp. 763-767
Author(s):  
Hui-Ting Wang ◽  
Qiang Li ◽  
Lin Zhou
Keyword(s):  
Three Dimensional ◽  
Supramolecular Network ◽  
Cadmium Nitrate ◽  
Two Dimensional ◽  
Thiocyanate Complex ◽  
Distorted Octahedral Coordination ◽  
Hydrogen Bonding Interactions ◽  
Dimensional Network ◽  
Distorted Octahedral ◽  
Nitrate Tetrahydrate

A cadmium–thiocyanate complex, poly[(1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane-κ4N)octakis-μ2-thiocyanato-κ8N:S;κ8S:N-tricadmium(II)], [Cd3(C8H14N3)2(NCS)8]n, was synthesized by the reaction of 1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane chloride, cadmium nitrate tetrahydrate and potassium thiocyanide in aqueous solution. In the crystal structure, there are two independent types of CdIIcation (one on a centre of inversion and one in a general position) and both are in distorted octahedral coordination environments, coordinated by N and S atoms from different ligands. Neighbouring CdIIcations are linked together by thiocyanate bridges to form a two-dimensional network. Hydrogen-bonding interactions are involved in the formation of a three-dimensional supramolecular network.

A trimethylsulfonium salt with a novel polymeric cadmate anion

2013 ◽  
Vol 69 (10) ◽  
pp. 1128-1131 ◽  
Author(s):  
Ming-Liang Liu
Keyword(s):  
Hydrogen Bonds ◽  
Coordination Mode ◽  
Three Dimensional ◽  
Dimensional Structure ◽  
Zigzag Chain ◽  
Two Dimensional ◽  
One Dimensional ◽  
Octahedral Environment ◽  
Distorted Octahedral ◽  
Cl Atoms

The title salt,catena-poly[trimethylsulfonium [μ2-chlorido-di-μ2-thiocyanato-cadmate(II)]] {(C3H9S)[CdCl(NCS)2]}n, consists of trimethylsulfonium cations sandwiched between layers of a two-dimensional polyanion. The CdIIcentre displays a distorted octahedral environment coordinated by two bridging Cl atoms, two thiocyanate N atoms and two thiocyanate S atoms. The thiocyanate groups adopt the μ-1,3-coordination mode and bridge the CdIIcentres into a one-dimensional zigzag chain extended along the [110] direction. The CdIIcentres of the zigzag chains are crosslinked by bridging Cl atoms, forming a two-dimensional polyanion. The two-dimensional anions are linked to layers of trimethylsulfonium cations by weak intermolecular C—H...Cl hydrogen bonds, forming the three-dimensional structure.

scholarly journals Crystal structures of two isostructural bivalent metal N-benzoylglycinates

2020 ◽  
Vol 76 (8) ◽  
pp. 1260-1265
Author(s):  
Kedar U. Narvekar ◽  
Bikshandarkoil R. Srinivasan
Keyword(s):  
Crystal Structures ◽  
Aqua Ligand ◽  
Distorted Octahedral Geometry ◽  
Central Metal ◽  
Bivalent Metal ◽  
One Dimensional ◽  
Hydrogen Bonding Interactions ◽  
Distorted Octahedral ◽  
Bivalent Metals ◽  
The One

The crystal structures of two coordination compounds of N-benzoylglycine, viz. catena-poly[[[diaquabis(N-benzoylglycinato)cobalt(II)]-μ-aqua] dihydrate], {[Co(C9H8NO3)2(H2O)3]·2H2O} n , 1, and catena-poly[[[diaquabis(N-benzoylglycinato)nickel(II)]-μ-aqua] dihydrate], {[Ni(C9H8NO3)2(H2O)3]·2H2O} n , 2, are described. The structures of 1 and 2 were reported previously [Morelock et al. (1979). J. Am. Chem. Soc. 101, 4858–4866] and redetermined in this work to determine the H-atom coordinates. In the isostructural compounds, the central metal is located on an inversion centre and exhibits a distorted octahedral geometry. A pair of terminal aqua ligands disposed trans to each other and a pair of monodentate N-benzoylglycinate ligands form the square base and account for four of the six vertices of the octahedron. A μ2-bridging aqua ligand links the bivalent metals into one-dimensional chains extending along the c-axis direction. The one-dimensional chains stabilized by O—H...O hydrogen bonds are interlinked by N—H...O and C—H...O hydrogen-bonding interactions.

The coordination chemistry of two symmetric fluorene-based organic ligands with cuprous chloride

2013 ◽  
Vol 69 (12) ◽  
pp. 1488-1493 ◽  
Author(s):  
Yan-Fei Liu ◽  
Chao-Wei Zhao ◽  
Jian-Ping Ma ◽  
Qi-Kui Liu ◽  
Yu-Bin Dong
Keyword(s):  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Helical Chain ◽  
Cuprous Chloride ◽  
Dimensional Chain ◽  
Two Dimensional ◽  
One Dimensional ◽  
Dimensional Network ◽  
The Difference ◽  
The One

Two novel symmetric fluorene-based ligands, namely, 2,7-bis(1H-imidazol-1-yl)-9,9-dimethyl-9H-fluorene [L1 or (I), C21H18N4] and 2,7-bis(1H-imidazol-1-yl)-9,9-dipropyl-9H-fluorene (L2), have been used to construct the coordination polymerscatena-poly[[dichloridodicopper(I)(Cu—Cu)]-μ-2,7-bis(1H-imidazol-1-yl)-9,9-dimethyl-9H-fluorene], [Cu2Cl2(C21H18N4)]n, (II), andcatena-poly[[tetra-μ2-chlorido-tetracopper(I)]-bis[μ-2,7-bis(1H-imidazol-1-yl)-9,9-dipropyl-9H-fluorene]], [Cu4Cl4(C25H26N4)2]n, (III). There are three types of C—H...N hydrogen bonds in (I), resulting a two-dimensional network in theabplane, including a chiral helical chain along thebaxis. Compounds (II) and (III) are related one-dimensional polymers. In both, CuIatoms connect the symmetric ligands (L1 orL2) into a one-dimensional chain. In (II), the {[CuICl2]−} unit, acting as a co-anion, adheres to the one-dimensional chain through a weak Cu...Cu interaction. However, in (III), the {[CuI2Cl4]2−} unit links two different chains into a one-dimensional rope-ladder-type chain. In addition, there are C—H...Cl hydrogen bonds and π–π interactions in the extended structures of (II) and (III), the difference is that the chains in (II) are linked into a two-dimensional network while the chains in (III) are stacked into a three-dimensional framework.

scholarly journals Crystal structure of bis[bis(1,4,7-triazacyclononane-κ3 N,N′,N′′)chromium(III)] tris(tetrachloridozincate) monohydrate from synchrotron X-ray data

2019 ◽  
Vol 75 (4) ◽  
pp. 428-431 ◽  
Author(s):  
Dohyun Moon ◽  
Jong-Ha Choi
Keyword(s):  
Crystal Packing ◽  
Three Dimensional ◽  
Distorted Octahedral Geometry ◽  
Water Molecules ◽  
X Ray ◽  
Hydrogen Bonding Interactions ◽  
Dimensional Network ◽  
Distorted Octahedral ◽  
The Mean ◽  
Cl Atoms

The structure of the title compound, [Cr(tacn)2]2[ZnCl4]3·H2O (tacn is 1,4,7-triazacyclononane; C6H15N3), has been determined from synchrotron X-ray data. Each CrIII cation is coordinated by the six N atoms from the two tacn ligands, displaying a distorted octahedral geometry. Three distorted tetrahedral [ZnCl4]2− anions and one lattice water molecule lie outside this coordination sphere. The Cr—N bond lengths are in the range 2.0621 (11) to 2.0851 (12) Å, while the mean inner N—Cr—N bond angle is 82.51 (5)°. The crystal packing is stabilized by hydrogen-bonding interactions with the N—H groups of the tacn ligands and the water O—H groups acting as donors, and the O atoms of the water molecules and Cl atoms of the [ZnCl4]2− anions as acceptors. Overall these contacts lead to the formation of a three-dimensional network.

scholarly journals Poly[[octaaqua-μ4-(benzene-1,2,4,5-tetracarboxylato)-dicobalt(II)] octahydrate]

2013 ◽  
Vol 69 (12) ◽  
pp. m680-m681 ◽  
Author(s):  
Magatte Camara ◽  
Modou Tine ◽  
Carole Daiguebonne ◽  
Olivier Guillou ◽  
Thierry Roisnel
Keyword(s):  
Three Dimensional ◽  
Distorted Octahedral Geometry ◽  
Water Molecules ◽  
Agar Gel ◽  
Hydrogen Bonding Interactions ◽  
Dimensional Network ◽  
Shaped Tube ◽  
Distorted Octahedral ◽  
Dilute Aqueous Solution ◽  
Polymeric Coordination

The title polymeric coordination compound, {[Co2(C10H2O8)(H2O)8]·8H2O}n, was obtained by slow diffusion of a dilute aqueous solution of CoCl2and the sodium salt of benzene-1,2,4,5-tetracarboxylic acid (H4btec) through an agar–agar gel bridge in a U-shaped tube. The two independent Co2+ions are each situated on an inversion centre and are coordinated in a slightly distorted octahedral geometry by four water O atoms and two carboxylate O atoms from two btec4−ligands (-1> symmetry), forming a layer parallel to (11-1). This layer can be described as a molecular two-dimensional square grid with the benzene rings at the nodes and the CoIIatoms connecting the nodes. O—H...O hydrogen-bonding interactions involving the coordinating water molecules, the carboxylate O atoms and lattice water molecules lead to the formation of a three-dimensional network.

A three-dimensional cadmium(II) coordination polymer: poly[[[μ-4,4′-(propane-1,3-diyl)dipyridine-κ2N:N](μ-3,3′-thiodipropionato-κ3O,O′:O)cadmium(II)] monohydrate]

2014 ◽  
Vol 70 (7) ◽  
pp. 712-714
Author(s):  
Xiao-Min Hao ◽  
Gang Chen ◽  
Chang-Sheng Gu ◽  
Ji-Wei Liu
Keyword(s):  
Coordination Polymer ◽  
Three Dimensional ◽  
Octahedral Coordination ◽  
Two Dimensional ◽  
One Dimensional ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Distorted Octahedral

In the title coordination polymer, {[Cd(C6H8O4S)(C13H14N2)]·H2O}n, the CdIIatom displays a distorted octahedral coordination, formed by three carboxylate O atoms and one S atom from three different 3,3′-thiodipropionate ligands, and two N atoms from two different 4,4′-(propane-1,3-diyl)dipyridine ligands. The CdIIcentres are bridged through carboxylate O atoms of 3,3′-thiodipropionate ligands and through N atoms of 4,4′-(propane-1,3-diyl)dipyridine ligands to form two different one-dimensional chains, which intersect to form a two-dimensional layer. These two-dimensional layers are linked by S atoms of 3,3′-thiodipropionate ligands from adjacent layers to form a three-dimensional network.

scholarly journals 2-Amino-5-chloropyridinium cis-diaquadioxalatochromate(III) sesquihydrate

2012 ◽  
Vol 68 (6) ◽  
pp. m824-m825 ◽  
Author(s):  
Ichraf Chérif ◽  
Jawher Abdelhak ◽  
Mohamed Faouzi Zid ◽  
Ahmed Driss
Keyword(s):  
Rotation Axis ◽  
Three Dimensional ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Water Molecules ◽  
Lattice Water ◽  
Compound C ◽  
Hydrogen Bonding Interactions ◽  
Distorted Octahedral ◽  
Independent Lattice

In the crystal structure of the title compound, (C5H6ClN2)[Cr(C2O4)2(H2O)2]·1.5H2O, the CrIII atom adopts a distorted octahedral geometry being coordinated by two O atoms of two cis water molecules and four O atoms from two chelating oxalate dianions. The cis-diaquadioxalatochromate(III) anions, 2-amino-5-chloropyridinium cations and uncoordinated water molecules are linked into a three-dimensional supramolecular array by O—H...O and N—H...O hydrogen-bonding interactions. One of the two independent lattice water molecules is situated on a twofold rotation axis.

scholarly journals Tris(1,10-phenanthroline-κ2 N,N′)cobalt(II) bis(2,4,5-tricarboxybenzoate) monohydrate

IUCrData ◽  
2019 ◽  
Vol 4 (1) ◽  
Author(s):  
Kai-Long Zhong ◽  
Guo-Qing Cao ◽  
Wei Song ◽  
Chao Ni
Keyword(s):  
Hydrogen Bonds ◽  
Network Structure ◽  
Rotation Axis ◽  
Complex Cation ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Dimensional Network ◽  
Distorted Octahedral

In the complex cation of the title salt, [Co(C12H8N2)3](C10H5O8)2·H2O, the CoII cation is situated on a twofold rotation axis and is coordinated in a distorted octahedral manner by six N atoms from three chelating 1,10-phenanthroline (phen) ligands. In the crystal, the non-coordinating 2,4,5-tricarboxybenzoate anions interact with each other via O—H...O hydrogen bonds, generating a two-dimensional network parallel to (100). Adjacent sheets are connected by waterO—H...Ocarboxylate hydrogen bonds, resulting in a three-dimensional network structure that surrounds the complex cations.

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