A two-dimensional cadmium(II) coordination polymer based on 1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane and thiocyanate ligands

2015 ◽  
Vol 71 (9) ◽  
pp. 763-767
Author(s):  
Hui-Ting Wang ◽  
Qiang Li ◽  
Lin Zhou
Keyword(s):  
Three Dimensional ◽  
Supramolecular Network ◽  
Cadmium Nitrate ◽  
Two Dimensional ◽  
Thiocyanate Complex ◽  
Distorted Octahedral Coordination ◽  
Hydrogen Bonding Interactions ◽  
Dimensional Network ◽  
Distorted Octahedral ◽  
Nitrate Tetrahydrate

A cadmium–thiocyanate complex, poly[(1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane-κ4N)octakis-μ2-thiocyanato-κ8N:S;κ8S:N-tricadmium(II)], [Cd3(C8H14N3)2(NCS)8]n, was synthesized by the reaction of 1-cyanomethyl-4-aza-1-azoniabicyclo[2.2.2]octane chloride, cadmium nitrate tetrahydrate and potassium thiocyanide in aqueous solution. In the crystal structure, there are two independent types of CdIIcation (one on a centre of inversion and one in a general position) and both are in distorted octahedral coordination environments, coordinated by N and S atoms from different ligands. Neighbouring CdIIcations are linked together by thiocyanate bridges to form a two-dimensional network. Hydrogen-bonding interactions are involved in the formation of a three-dimensional supramolecular network.

A two-dimensional cadmium(II) polymer based on nicotinic acid and thiocyanate ligands

2015 ◽  
Vol 71 (9) ◽  
pp. 820-823
Author(s):  
Lin Zhou ◽  
Hui-Ting Wang
Keyword(s):  
Nicotinic Acid ◽  
Three Dimensional ◽  
Supramolecular Network ◽  
Cadmium Nitrate ◽  
Two Dimensional ◽  
Thiocyanate Complex ◽  
Hydrogen Bond Interactions ◽  
Dimensional Network ◽  
Distorted Octahedral ◽  
Nitrate Tetrahydrate

A cadmium–thiocyanate complex, poly[[bis(nicotinic acid-κN)di-μ-thiocyanato-κ2N:S;κ2S:N-cadmium(II)] monohydrate], {[Cd(NCS)2(C6H5NO2)2]·H2O}n, was synthesized by the reaction of nicotinic acid, cadmium nitrate tetrahydrate and potassium thiocyanide in aqueous solution. In the crystal structure, each CdIIcation is in a distorted octahedral coordination environment, coordinated by the N and S atoms of nicotinic acid and thiocyanate ligands. Neighbouring CdIIcations are linked together by thiocyanate bridges to form a two-dimensional network. Hydrogen-bond interactions between the uncoordinated solvent water molecules and the organic ligands result in the formation of the three-dimensional supramolecular network.

A one-dimensional CdIIcoordination polymer constructed from 4-(dimethylamino)pyridinium-1-acetate ligands and thiocyanate coordination bridges

2015 ◽  
Vol 71 (7) ◽  
pp. 549-553 ◽  
Author(s):  
Hui-Ting Wang ◽  
Lin Zhou
Keyword(s):  
Supramolecular Network ◽  
Zigzag Chain ◽  
Cadmium Nitrate ◽  
Thiocyanate Complex ◽  
One Dimensional ◽  
Distorted Octahedral Coordination ◽  
Hydrogen Bond Interactions ◽  
Acetate Ligand ◽  
Distorted Octahedral ◽  
Nitrate Tetrahydrate

A new cadmium–thiocyanate complex, namelycatena-poly[1-carboxymethyl-4-(dimethylamino)pyridinium [cadmium(II)-tri-μ-thiocyanato-κ4N:S;κ2S:N] [[[4-(dimethylamino)pyridinium-1-acetate-κ2O,O′]cadmium(II)]-di-μ-thiocyanato-κ2N:S;κ2S:N]], {(C9H13N2O2)[Cd(NCS)3][Cd(NCS)2(C9H12N2O2)]}n, was synthesized by the reaction of 4-(dimethylamino)pyridinium-1-acetate, cadmium nitrate tetrahydrate and potassium thiocyanide in aqueous solution. In the crystal structure, two types of CdIIatoms are observed in distorted octahedral coordination environments. One type of CdIIatom is coordinated by two O atoms from the carboxylate group of the 4-(dimethylamino)pyridinium-1-acetate ligand and by two N atoms and two S atoms from four different thiocyanate ligands, while the second type of CdIIatom is coordinated by three N atoms and three S atoms from six different thiocyanate ligands. Neighbouring CdIIatoms are linked by thiocyanate bridges to form a one-dimensional zigzag chain and a one-dimensional coordination polymer. Hydrogen-bond interactions are involved in the formation of the supramolecular network.

scholarly journals Crystal structure offac-trichlorido[tris(pyridin-2-yl-N)amine]chromium(III)

2015 ◽  
Vol 71 (1) ◽  
pp. 73-75 ◽  
Author(s):  
Yukiko Yamaguchi-Terasaki ◽  
Takashi Fujihara ◽  
Akira Nagasawa ◽  
Sumio Kaizaki
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Complex Molecule ◽  
Three Dimensional ◽  
Mirror Plane ◽  
Neutral Complex ◽  
Distorted Octahedral Coordination ◽  
Hydrogen Bonding Interactions ◽  
Dimensional Network ◽  
Distorted Octahedral

In the neutral complex molecule of the title compound,fac-[CrCl3(tpa)] [tpa is tris(pyridin-2-yl)amine; C15H12N4], the CrIIIion is bonded to three N atoms that are constrained to afacialarrangement by the tpa ligand and by three chloride ligands, leading to a distorted octahedral coordination sphere. The average Cr—N and Cr—Cl bond lengths are 2.086 (5) and 2.296 (4) Å, respectively. The complex molecule is located on a mirror plane. In the crystal, a combination of C—H...N and C—H...Cl hydrogen-bonding interactions connect the molecules into a three-dimensional network.

The two-dimensional coordination polymer poly[diaqua(μ2-1H-imidazo[4,5-f][1,10]phenanthroline)-μ4-sulfato-μ3-sulfato-dicadmium(II)]

2014 ◽  
Vol 70 (8) ◽  
pp. 770-772 ◽  
Author(s):  
Xiao-Min Hao ◽  
Gang Chen ◽  
Chang-Sheng Gu ◽  
Ji-Wei Liu
Keyword(s):  
Coordination Polymer ◽  
Three Dimensional ◽  
Supramolecular Network ◽  
Two Dimensional ◽  
Coordination Environment ◽  
One Dimensional ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral ◽  
Trigonal Prismatic ◽  
Distorted Octahedral Coordination Environment

In the title coordination polymer, [Cd2(SO4)2(C13H8N4)(H2O)2]n, there are two crystallographically independent CdIIcentres with different coordination geometries. The first CdIIcentre is hexacoordinated by four O atoms of four sulfate ligands, one water O atom and one N atom of a 1H-imidazo[4,5-f][1,10]phenanthroline (IP) ligand, giving a distorted octahedral coordination environment. The second CdIIcentre is heptacoordinated by four O atoms of three sulfate ligands, one water O atom and two N atoms of one chelating IP ligand, resulting in a distorted monocappedanti-trigonal prismatic geometry. The symmetry-independent CdIIions are bridged in an alternating fashion by sulfate ligands, forming one-dimensional ladder-like chains which are connected through the IP ligands to form two-dimensional layers. These two-dimensional layers are linked by interlayer hydrogen bonds, leading to the formation of a three-dimensional supramolecular network.

A new two-dimensional polymeric cadmium(II) complex containing dicyanamide bridging ligands

2017 ◽  
Vol 73 (11) ◽  
pp. 885-888 ◽  
Author(s):  
Yang Lu ◽  
Wei-Qiang Liao ◽  
Xiu-Ni Hua
Keyword(s):  
Distorted Octahedral Geometry ◽  
Supramolecular Network ◽  
Cadmium Nitrate ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Bridging Ligands ◽  
Hydrogen Bond Interactions ◽  
Anionic Layer ◽  
Distorted Octahedral ◽  
Nitrate Tetrahydrate

As part of an exploration of new coordination polymers, a cadmium-dicyanamide complex, namely poly[benzyltriethylammonium [tri-μ-dicyanamido-κ6 N 1:N 5-cadmium(II)]], {(C13H22N)[Cd(C2N3)3]} n , has been synthesized by the reaction of benzyltriethylammonium bromide, cadmium nitrate tetrahydrate and sodium dicyanamide in aqueous solution, and characterized by single-crystal X-ray diffraction at room temperature. In the crystal structure, each CdII cation is coordinated by six nitrile N atoms from six anionic dicyanamide (dca) ligands to furnish a slightly distorted octahedral geometry. Neighbouring CdII cations are linked by dicyanamide bridges to construct a two-dimensional anionic layer coordination polymer. One amide N atom in the bridging dca ligand is disordered over two sites. The cations lie between the anionic frameworks and there are no hydrogen-bond interactions between the cations and anions. The organic cations are not involved in the formation of the supramolecular network.

scholarly journals (2,2′-Bipyrazine-κ2N1,N1′)[1,2-bis(diphenylphosphanyl)methane-κP]tricarbonylrhenium(I) trifluoromethanesulfonate monohydrate

IUCrData ◽  
2017 ◽  
Vol 2 (6) ◽  
Author(s):  
D. Paul Rillema ◽  
Venugopal Komreddy ◽  
Nilmini K. Senaratne ◽  
David M. Eichhorn
Keyword(s):  
Water Molecule ◽  
Three Dimensional ◽  
Phenyl Group ◽  
Carbonyl Groups ◽  
Coordination Environment ◽  
Distorted Octahedral Coordination ◽  
Hydrogen Bonding Interactions ◽  
Dimensional Network ◽  
Distorted Octahedral ◽  
Distorted Octahedral Coordination Environment

The title compound, [Re(C8H6N4)(C25H22P2)(CO)3]CF3SO3·H2O, crystallizes with one [Re(C8N4H6){P(Ph)2CH2P(Ph)2}(CO)3]+cation, where Ph is a phenyl group, one CF3SO3−anion and one water molecule of hydration. The three C atoms of thefacialoriented carbonyl groups, two N atoms from the bipyrazine ligand and one P atom from the (bis)diphenylphosphanylmethane ligand define a distorted octahedral coordination environment about the central ReIatom. The Re—Ccarbonylbond lengthtransto the P atom is longer than the the two Re—Ccarbonylbond lengths in the plane with the bipyrazine ligand. Hydrogen-bonding interactions between the solvent water molecule and the cation, as well as weak C—H...O interactions, consolidate a three-dimensional network structure.

A two-dimensional anionic CdIIpolymer constructed through dicyanamide coordination bridges

2015 ◽  
Vol 71 (8) ◽  
pp. 717-720 ◽  
Author(s):  
Hui-Ting Wang ◽  
Lin Zhou ◽  
Xiao-Li Wang
Keyword(s):  
Crystal Structure ◽  
Solid Phase ◽  
Inorganic Compounds ◽  
Three Dimensional ◽  
Ferroelectric Materials ◽  
Organic Cations ◽  
Supramolecular Network ◽  
Cadmium Nitrate ◽  
Two Dimensional ◽  
Nitrate Tetrahydrate

In the search for potential ferroelectric materials, molecular-based one-, two- and three-dimensional cadmium(II) organic–inorganic compounds have been of interest as they often display solid–solid phase transitions induced by a variation in temperature. A new cadmium dicyanamide complex, poly[4-dimethylamino-1-ethylpyridin-1-ium [tri-μ-dicyanamido-κ6N1:N5-cadmium(II)]], {(C9H15N2)[Cd(C2N3)3]}n, was synthesized by the reaction of 4-dimethylamino-1-ethylpyridin-1-ium bromide, cadmium nitrate tetrahydrate and sodium dicyanamide in aqueous solution. In the crystal structure, each CdIIcation is octahedrally coordinated by six terminal N atoms from six anionic dicyanamide (dca) ligands. Neighbouring CdIIcations are linked together by dicyanamide bridges to form a two-dimensional coordination polymer. The organic cations are not involved in the formation of the supramolecular network.

scholarly journals catena-Poly[[[bis(1,10-phenanthroline-κ2N,N′)manganese(II)]-μ-9,10-dioxoanthracene-1,5-disulfonato-κ2O1:O5] tetrahydrate]

2009 ◽  
Vol 65 (6) ◽  
pp. m695-m696 ◽  
Author(s):  
Jia Jia ◽  
Wen Feng ◽  
Hong-Kun Zhao ◽  
En-Cui Yang
Keyword(s):  
Three Dimensional ◽  
Supramolecular Network ◽  
Central Ring ◽  
Coordination Environment ◽  
Distorted Octahedral Coordination ◽  
Hydrogen Bonding Interactions ◽  
Distorted Octahedral ◽  
A Chain ◽  
Phenanthroline Ligands ◽  
Distorted Octahedral Coordination Environment

The title complex, {[Mn(C14H6O8S2)(C12H8N2)2]·4H2O}n, exhibits a chain-like polymeric structure with 9,10-dioxoanthracene-1,5-disulfonate anions bridging MnIIatoms in a bis-monodentate mode. The unique MnIIatom is located on a crystallographic centre of inversion. Four N atoms from two chelating 1,10-phenanthroline ligands and two sulfonate O atoms from two symmetry-related 9,10-dioxoanthracene-1,5-disulfonate anions give rise to a slightly distorted octahedral coordination environment around the MnIIcentre. The centroid of the central ring of the anthraquinone ligand represents another crystallographic centre of inversion. In the crystal structure, interligand π–π stacking [centroid-to-centroid distances 3.532 (1) and 3.497 (3) Å] and intermolecular O—H...O hydrogen-bonding interactions assemble the chains into a three-dimensional supramolecular network.

scholarly journals Diaquabis(propane-1,3-diamine)nickel(II) bis(propane-1,3-diamine)disulfatonickelate(II)

2012 ◽  
Vol 68 (4) ◽  
pp. m400-m401
Author(s):  
Julia A. Rusanova
Keyword(s):  
Hydrogen Bonds ◽  
Complex Anion ◽  
Complex Cation ◽  
Two Dimensional ◽  
Distorted Octahedral Coordination ◽  
Hydrogen Bonding Interactions ◽  
Dimensional Network ◽  
Distorted Octahedral ◽  
Coordinated Water ◽  
Complex Anions

The ionic NiIItitle complex, [Ni(C3H10N2)2(H2O)2][Ni(SO4)2(C3H10N2)2], is built up of [Ni(dipr)2(H2O)2]2+complex cations and [Ni(dipr)2(SO4)2]2−complex anions (dipr is propane-1,3-diamine). Both NiIIatoms display a slightly distorted octahedral coordination and are located on inversion centers. There are several types of hydrogen-bonding interactions, which connect complex cations and anions into a two-dimensional network parallel to (010). Hydrogen bonds formed by the axially coordinated water molecule of the complex cation and one of the O atoms of the sulfate groups of the complex anion (first type) link them into chains along thecaxis. These chains are linked to each other through hydrogen bonds formed by an O atom (second type) of the SO4groups and NH2groups of the ligand of the complex cations from neighboring chains, forming a two-dimensional hydrogen-bonded net perpendicular to thebaxis. The third type of O atoms of the sulfate groups of the complex anion are also linked into chains by a combination of both previously described types of H-atom connections.

A three-dimensional cadmium(II) coordination polymer: poly[[[μ-4,4′-(propane-1,3-diyl)dipyridine-κ2N:N](μ-3,3′-thiodipropionato-κ3O,O′:O)cadmium(II)] monohydrate]

2014 ◽  
Vol 70 (7) ◽  
pp. 712-714
Author(s):  
Xiao-Min Hao ◽  
Gang Chen ◽  
Chang-Sheng Gu ◽  
Ji-Wei Liu
Keyword(s):  
Coordination Polymer ◽  
Three Dimensional ◽  
Octahedral Coordination ◽  
Two Dimensional ◽  
One Dimensional ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Distorted Octahedral

In the title coordination polymer, {[Cd(C6H8O4S)(C13H14N2)]·H2O}n, the CdIIatom displays a distorted octahedral coordination, formed by three carboxylate O atoms and one S atom from three different 3,3′-thiodipropionate ligands, and two N atoms from two different 4,4′-(propane-1,3-diyl)dipyridine ligands. The CdIIcentres are bridged through carboxylate O atoms of 3,3′-thiodipropionate ligands and through N atoms of 4,4′-(propane-1,3-diyl)dipyridine ligands to form two different one-dimensional chains, which intersect to form a two-dimensional layer. These two-dimensional layers are linked by S atoms of 3,3′-thiodipropionate ligands from adjacent layers to form a three-dimensional network.

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