trans-Bis(ethylenediamine)bis(trifluoroacetato)copper(II)

2007 ◽  
Vol 63 (3) ◽  
pp. m658-m659 ◽  
Author(s):  
Elena V. Karpova ◽  
Maxim A. Zakharov ◽  
Sergey I. Gutnikov ◽  
Alexandr I. Boltalin
Keyword(s):  
Hydrogen Bonds ◽  
Crystal Packing ◽  
Octahedral Geometry ◽  
Title Complex ◽  
Distorted Octahedral Geometry ◽  
Distorted Octahedral

The title complex, [Cu(H2NCH2CH2NH2)2(CF3COO)2], possesses a crystallographically imposed centre of symmetry. The Cu(II) atom is coordinated by four N atoms [Cu—N 1.985 (2), 2.015 (2) Å] from two chelate ethylenediamine ligands and two O atoms [Cu—O 2.579 (2) Å] from two trifluoroacetate anions in a distorted octahedral geometry. The crystal packing is stabilized by weak intermolecular N—H...O hydrogen bonds.

scholarly journals cis-Chloridobis(4,4′-dimethyl-2,2′-bipyridine)nitrosylruthenium(II) bis(hexafluorophosphate)

IUCrData ◽  
2017 ◽  
Vol 2 (7) ◽  
Author(s):  
Hasan Shamran Mohammed ◽  
Marine Tassé ◽  
Isabelle Malfant ◽  
Laure Vendier
Keyword(s):  
Hydrogen Bonds ◽  
Crystal Packing ◽  
Three Dimensional ◽  
Chloride Ion ◽  
Octahedral Geometry ◽  
Title Complex ◽  
The Other ◽  
Distorted Octahedral Geometry ◽  
Rotation Axes ◽  
Distorted Octahedral

In the cation of the title complex, [RuCl(NO)(C12H12N2)2](PF6)2, the central RuII ion is sixfold coordinated by a chloride ion and a nitrosyl ligand, which are cis to one another, and by four N atoms of two 4,4′-dimethyl-2,2′-bipyridine ligands, in a slightly distorted octahedral geometry. One of the PF6 − anions is located in a general position, while the other is composed of two half PF6 − anions located on twofold rotation axes. The crystal packing is dominated by C—H...F hydrogen bonds, leading to the formation of a three-dimensional supramolecular structure. There are also C—H...Cl hydrogen bonds present.

Bis[(3-hydroxy-2-naphthyl)(2-pyridylmethylenehydrazono)methanolato]nickel(II)

2007 ◽  
Vol 63 (11) ◽  
pp. m2667-m2667 ◽  
Author(s):  
Wenjun Kang ◽  
Shizhu Sun ◽  
Dacheng Li ◽  
Daqi Wang ◽  
Jianmin Dou
Keyword(s):  
Hydrogen Bonds ◽  
Molecular Conformation ◽  
Crystal Packing ◽  
Octahedral Geometry ◽  
Title Complex ◽  
Distorted Octahedral Geometry ◽  
Distorted Octahedral

In the title complex, [Ni(C17H12N3O2)2], the NiII ion is coordinated by two O [Ni—O = 2.066 (3) and 2.068 (3) Å] and four N [Ni—N = 1.982 (3)–2.120 (3)Å] atoms in a distorted octahedral geometry. Two intramolecular O—H...N hydrogen bonds contribute to the molecular conformation. Weak intermolecular C—H...O hydrogen bonds stabilize the crystal packing.

scholarly journals Bis[2-(2-hydroxymethyl)pyridine-κ2N,O](pivalato-κO)copper(II)

2012 ◽  
Vol 68 (8) ◽  
pp. m1055-m1055 ◽  
Author(s):  
M. Mobin Shaikh ◽  
Veenu Mishra ◽  
Priti Ram ◽  
Anil Birla
Keyword(s):  
Hydrogen Bond ◽  
Crystal Packing ◽  
Octahedral Geometry ◽  
Title Complex ◽  
Distorted Octahedral Geometry ◽  
Pyridine Ligands ◽  
Hydrogen Bond Interactions ◽  
Distorted Octahedral

The structure of the centrosymmetric title complex, [Cu(C5H9O2)2(C6H7NO)2], has the CuIIatom on a centre of inversion. The CuIIatom is six-coordinate with a distorted octahedral geometry, defined by the N and O atoms of the chelating 2-(2-hydroxymethyl)pyridine ligands and two carboxylate O atoms from two monodentate pivalate ions. The crystal packing is stabilized by intermolecular C—H...O and intramolecular O—H...O hydrogen-bond interactions.

scholarly journals Diaquabis(2,2′-bi-1H-imidazole)manganese(II) benzene-1,4-dicarboxylate

2012 ◽  
Vol 68 (6) ◽  
pp. m829-m829
Author(s):  
Lining Yang ◽  
Yanxiang Zhi ◽  
Jiahui Hei ◽  
Yanqing Miao
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Crystal Packing ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Water Molecules ◽  
Asymmetric Unit ◽  
Π Interactions ◽  
Centroid Distance ◽  
Distorted Octahedral

The asymmetric unit of the title compound, [Mn(C6H6N4)2(H2O)2](C8H4O4), contains one-half each of the centrosymmetric cation and anion. The MnII atom is coordinated by four N atoms [Mn—N = 2.2168 (14) and 2.2407 (14) Å] from two 2,2′-biimidazole ligands and two water molecules [Mn—O = 2.2521 (14) Å] in a distorted octahedral geometry. Intermolecular N—H...O and O—H...O hydrogen bonds consolidate the crystal packing, which also exhibits π–π interactions between five-membered rings, with a centroid–centroid distance of 3.409 (2) Å.

scholarly journals fac-[1,2-Bis(pyridin-4-yl)ethane-κN]tricarbonyl(1,10-phenanthroline-κ2N,N′)rhenium(I) hexafluoridophosphate acetonitrile monosolvate

2014 ◽  
Vol 70 (7) ◽  
pp. m278-m279 ◽  
Author(s):  
Silvana Guilardi ◽  
Antonio Otavio Toledo Patrocinio ◽  
Sinval Fernandes de Sousa ◽  
Javier Ellena
Keyword(s):  
Hydrogen Bonds ◽  
Crystal Packing ◽  
Solvent Molecule ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Asymmetric Unit ◽  
Carbonyl Ligands ◽  
Distorted Octahedral ◽  
Phenanthroline Ligand ◽  
Solvent Molecules

The asymmetric unit of the title compound, [Re(C12H8N2)(C12H12N2)(CO)3]PF6.·CH3CN, contains one cation, one hexafluoridophosphate anion and one acetonitrile solvent molecule. The ReIion is coordinated by two N atoms from the 1,10-phenanthroline ligand and one N atom from the 1,2-bis(pyridin-4-yl)ethane ligand [mean Re—N = 2.191 (15) Å] and by three carbonyl ligands [mean Re—C = 1.926 (3) Å] in a distorted octahedral geometry. The electrostatic forces and weak C—H...F(O) hydrogen bonds pack cations and anions into the crystal with voids of 82 Å3, which are filled by solvent molecules. The crystal packing exhibits short intermolecular O...O distance of 2.795 (5) Å between two cations related by inversion.

scholarly journals [(Pyridine-2,6-dicarboxylato)copper(II)]-μ-(pyridine-2,6-dicarboxylato)-[bis(ethylenediamine)copper(II)]-μ-(pyridine-2,6-dicarboxylato)-[(pyridine-2,6-dicarboxylato)copper(II)] ethylenediamine monosolvate tetrahydrate

2012 ◽  
Vol 68 (6) ◽  
pp. m830-m831 ◽  
Author(s):  
Amir Shokooh Saljooghi ◽  
Hadi Amiri Rudbari ◽  
Francesco Nicolò ◽  
Maliheh Zahmati ◽  
Fatemeh Delavar Mendi
Keyword(s):  
Crystal Structure ◽  
Aqueous Solution ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Octahedral Geometry ◽  
Title Complex ◽  
Distorted Octahedral Geometry ◽  
Acetate Dihydrate ◽  
Carboxylate Groups ◽  
Distorted Octahedral

The title compound, [Cu3(C7H3NO4)4(C2H8N2)2]·C2H8N2·4H2O, was obtained by the reaction of copper(II) acetate dihydrate with pyridine-2,6-dicarboxylic acid (H2dipic) and ethylenediamine (en) in an aqueous solution. All of the CuII atoms in the trinuclear centrosymmetric title complex are six-coordinated in a distorted octahedral geometry with N2O4 and N4O2 environments for the outer and central CuII atoms, respectively. Various interactions, including numerous O—H...O and C—H...O hydrogen bonds and C—O...π stacking of the pyridine and carboxylate groups [O...centroid distances = 3.669 (2) and 3.668 (2) Å] are observed in the crystal structure.

scholarly journals trans-Diaquabis[(E)-3-(dimethylamino)-1-(2-pyridyl)prop-2-en-1-one-κ2N1,O]cobalt(II) dinitrate dihydrate

2009 ◽  
Vol 65 (6) ◽  
pp. m633-m633 ◽  
Author(s):  
Jian-Hong Bi
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Crystal Packing ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Water Molecules ◽  
Inversion Center ◽  
Distorted Octahedral

In the title compound, [Co(C10H12N2O)2(H2O)2](NO3)2·2H2O, the CoIIion, located on an inversion center, istrans-coordinated by twoN,O-bidentate chelating (E)-3-(dimethylamino)-1-(2-pyridyl)prop-2-en-1-one ligands and by two water molecules in a slightly distorted octahedral geometry. Intermolecular O—H...O hydrogen bonds link the cations, anions and water molecules into layers parallel to theacplane. The crystal packing also exhibits weak intermolecular C—H...O hydrogen bonds.

scholarly journals Caesium bis(5-bromosalicylaldehyde thiosemicarbazonato-κ3O,N,S)ferrate(III): supramolecular arrangement of low-spin FeIIIcomplex anions mediated by Cs+cations

2015 ◽  
Vol 71 (3) ◽  
pp. 169-174
Author(s):  
Robyn Elizabeth Powell ◽  
Carl H. Schwalbe ◽  
Graham J. Tizzard ◽  
Petra J. van Koningsbruggen
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Spin State ◽  
Structure Determination ◽  
Octahedral Geometry ◽  
Title Complex ◽  
Crystal Structure Determination ◽  
Distorted Octahedral Geometry ◽  
Synthesis And Crystal Structure ◽  
Distorted Octahedral

The synthesis and crystal structure determination (at 293 K) of the title complex, Cs[Fe(C8H6BrN3OS)2], are reported. The compound is composed of two dianionicO,N,S-tridentate 5-bromosalicylaldehyde thiosemicarbazonate(2−) ligands coordinated to an FeIIIcation, displaying a distorted octahedral geometry. The ligands are orientated in two perpendicular planes, with the O- and S-donor atoms incispositions and the N-donor atoms intranspositions. The complex displays intermolecular N—H...O and N—H...Br hydrogen bonds, creatingR44(18) rings, which link the FeIIIunits in theaandbdirections. The FeIIIcation is in the low-spin state at 293 K.

Triaquachloridobis[4-(dimethylamino)benzaldehyde-κO]nickel(II) chloride

2007 ◽  
Vol 63 (11) ◽  
pp. m2819-m2819 ◽  
Author(s):  
Qiang Wang ◽  
Da-Qi Wang ◽  
Yu-Ying Sun
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Octahedral Geometry ◽  
Title Complex ◽  
Distorted Octahedral Geometry ◽  
Water Molecules ◽  
Two Dimensional ◽  
Distorted Octahedral ◽  
The Mean ◽  
Cl Atom

In the title complex, [NiCl(C9H11NO)2(H2O)3]Cl, the NiII ion is six-coordinated by one Cl atom [Ni—Cl = 2.3712 (11) Å], two O atoms from two 4-(dimethylamino)benzaldehyde (L) ligands and three water molecules in a distorted octahedral geometry [Ni—O = 2.076 (3)–2.094 (3) Å]. The mean planes of the two L ligands make a dihedral angle of 65.8 (1)°. In the crystal structure, intermolecular O—H...Cl hydrogen bonds link cations and anions into two-dimensional sheets parallel to the ab plane, with the L ligands protruding above and below.

scholarly journals Bis(2,2′-bipyridine)[1,9-bis(diphenylphosphanyl)-1,2,3,4,6,7,8,9-octahydropyrimido[1,2-a]pyrimidin-5-ium]ruthenium(II) hexafluoridophosphate dibromide dichloromethane disolvate monohydrate

2013 ◽  
Vol 69 (12) ◽  
pp. m640-m641 ◽  
Author(s):  
Congcong Shang ◽  
Laure Vendier ◽  
Pierre Sutra ◽  
Alain Igau
Keyword(s):  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Octahedral Geometry ◽  
Title Complex ◽  
Distorted Octahedral Geometry ◽  
Water Molecules ◽  
Dimensional Network ◽  
Distorted Octahedral ◽  
Solvent Molecules ◽  
Cl Atom

In the cation of the title complex, [Ru(C31H32N3P2)(C10H8N2)2](PF6)(Br)2·2CH2Cl2·H2O, the ruthenium ion is coordinated in a distorted octahedral geometry by two 2,2′-bipyridine (bpy) ligands and a chelating cationicN-diphenylphosphino-1,3,4,6,7,8-hexahydro-2-pyrimido[1,2-a]pyrimidine [(PPh2)2-hpp] ligand. The tricationic charge of the complex is balanced by two bromide and one hexafluoridophosphate counter-anions. The compound crystallized with two molecules of dichloromethane (one of which is equally disordered about a Cl atom) and a water molecule. In the crystal, one of the Br anions bridges two water moleculesviaO—H...Br hydrogen bonds, forming a centrosymmetric diamond-shapedR42(8) motif. The cation and anions and the solvent molecules are linkedviaC—H...F, C—H...Br, C—H...Cl and C—H...O hydrogen bonds, forming a three-dimensional network.

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