(Acetylacetonato-κ2O,O′)carbonyl[tris(4-chlorophenyl)phosphane-κP]rhodium(I)
2012 ◽
Vol 68
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pp. m509-m509
The title compound, [Rh(C5H7O2)(C18H12Cl3P)(CO)], contains the bidentate acetylacetonate ligand coordinated to the RhIatom, forming a chelate ring [Rh—O = 2.0327 (15) and 2.0613 (14) Å]. The RhIatom is additionally coordinated by one P [Rh—P = 2.2281 (6) Å] and one carbonyl C [Rh—C = 1.812 (2) Å] atom, resulting in a slightly distorted square-planar geometry. The molecules are packed to minimize steric hindrance with the phosphanes positioned above and below the slightly distorted square geometrical plane.
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