trans-Dichloridobis[dicyclohexyl(phenyl)phosphane-κP]palladium(II)
2012 ◽
Vol 68
(4)
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pp. m404-m404
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Keyword(s):
The title compound, [PdCl2{P(C6H11)2(C6H5)}2], forms a monomeric complex with atrans-square-planar geometry. The Pd—P bond lengths are 2.3343 (5) Å, as the Pd atom lies on an inversion centre, while the Pd—Cl bond lengths are 2.3017 (4) Å. The observed structure was found to be closely related to [PdCl2{P(C6H11)3}2] [Grushinet al.(1994).Inorg. Chem.33, 4804–4806], [PdBr2{P(C6H11)3}2] [Clarkeet al.(2003).Dalton Trans.pp. 4393–4394] and [PdCl2P(C6H11)2(C7H7)}2] [Vuotiet al.(2008).Eur. J. Inorg. Chem.pp. 397–407] (C6H11is cyclohexyl and C7H7iso-tolyl). One of the cyclohexyl rings is disordered with the phenyl ring in a 0.587 (9):413 (9) ratio. Five long-range C—H...Cl interactions were observed within the structure.
2013 ◽
Vol 69
(2)
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pp. m117-m118
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2014 ◽
Vol 70
(2)
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pp. 165-168
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Keyword(s):
2006 ◽
Vol 62
(7)
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pp. m1533-m1534
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Keyword(s):
2009 ◽
Vol 65
(6)
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pp. m673-m673
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Keyword(s):
2006 ◽
Vol 62
(5)
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pp. m1038-m1039
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Keyword(s):
2006 ◽
Vol 62
(5)
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pp. m1130-m1131
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Keyword(s):
2006 ◽
Vol 62
(5)
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pp. m974-m976
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Keyword(s):
2007 ◽
Vol 63
(11)
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pp. m2866-m2866
Keyword(s):
2007 ◽
Vol 63
(11)
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pp. m2758-m2758
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2012 ◽
Vol 68
(4)
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pp. m509-m509