Bis{benzyl 2-[4-(4-methoxyphenyl)butan-2-ylidene]hydrazinecarbodithioato-κ2
N
2,S}nickel(II)
2012 ◽
Vol 68
(6)
◽
pp. m725-m726
◽
Keyword(s):
The complete molecule of the title complex, [Ni(C19H21N2OS2)2], is generated by the application of twofold symmetry. The NiII atom is N,S-chelated by two hydrazinecarbodithioate ligands, which provide an N2S2 donor set that defines a distorted square-planar geometry, the S atoms being approximately cis. The conformation of the chelate ring is an envelope with the NiII atom being the flap atom. The dihedral angle between the least-squares planes through the chelate rings = 30.10 (6)°. Supramolecular chains propagated by glide symmetry along the c axis and mediated by C—H...N contacts feature in the crystal packing.
2012 ◽
Vol 68
(4)
◽
pp. m471-m472
◽
Keyword(s):
Keyword(s):
2012 ◽
Vol 68
(6)
◽
pp. m834-m834
◽
Keyword(s):
2015 ◽
Vol 71
(6)
◽
pp. 430-434
◽
Keyword(s):
2012 ◽
Vol 68
(4)
◽
pp. m440-m440
Keyword(s):
2012 ◽
Vol 68
(4)
◽
pp. m519-m519
Keyword(s):
Keyword(s):
2019 ◽
Vol 75
(10)
◽
pp. 1486-1489
Keyword(s):
2016 ◽
Vol 72
(1)
◽
pp. 66-68
◽
Keyword(s):
2014 ◽
Vol 70
(7)
◽
pp. o766-o767
◽
Keyword(s):