Di-μ-oxido-bis({2,2′-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}titanium(IV)) chloroform disolvate
2013 ◽
Vol 69
(11)
◽
pp. m626-m627
◽
Keyword(s):
In the title compound, [Ti2(C16H14N2O2)2O2]·2CHCl3, the TiIVatom in the centrosymmetric complex has a distorted octahedral N2O4coordination environment and is linkedviatwo μ2-oxido bridges into a dinuclear centrosymmetric complex, with a Ti...Ti separation of 2.7794 (8) Å. In the salen (N,N′-ethylenebis(salicylimine)) ligand, the two salicylimine units make a dihedral angle of 45.31 (5)°. The complex molecules are stacked parallel to [100], forming channels in which the solvent chloroform molecules are located. C—H...O hydrogen-bonding interactions between the complex molecules and the solvent molecules consolidate the crystal packing.
2012 ◽
Vol 68
(4)
◽
pp. m390-m391
◽
2014 ◽
Vol 70
(12)
◽
pp. m390-m391
2014 ◽
Vol 70
(10)
◽
pp. 164-166
◽
2014 ◽
Vol 70
(9)
◽
pp. 142-144
◽
2015 ◽
Vol 71
(9)
◽
pp. 1067-1069
2007 ◽
Vol 63
(11)
◽
pp. o4219-o4219
◽
Keyword(s):
2009 ◽
Vol 65
(6)
◽
pp. o1402-o1402
Keyword(s):
2015 ◽
Vol 71
(9)
◽
pp. m164-m165
2015 ◽
Vol 71
(2)
◽
pp. m40-m41
◽