Crystal structure of bis{2-[(2-hydroxyethyl)amino]ethanol-κ3O,N,O′}copper(II) terephthalate
2014 ◽
Vol 70
(11)
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pp. m372-m373
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Keyword(s):
The molecular components of the title salt, [Cu(C4H11NO2)2](C8H4O4), are one CuIIcationO,N,O′-chelated by two tridentate 2-[(2-hydroxyethyl)amino]ethanol ligands, and a terephthalate counter-dianion, located about a centre of inversion. The complex CuIIcation is located about a centre of inversion and shows typical Jahn–Teller distortion, with two short Cu—O and two short Cu—N bonds in the equatorial plane and two long Cu—O bonds to the axial atoms. The cations are arranged in sheets parallel to (100), with the centrosymmetric terephthalate anions located between the sheets. Each anion is the acceptor of four O—H...O and two N—H...O hydrogen bonds, forming a three-dimensional network structure.
Keyword(s):
2017 ◽
Vol 73
(6)
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pp. 442-446
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Keyword(s):
2016 ◽
Vol 72
(5)
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pp. 751-755
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2015 ◽
Vol 71
(4)
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pp. m85-m86
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2016 ◽
Vol 72
(5)
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pp. 616-619
2016 ◽
Vol 72
(4)
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pp. 502-504
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2017 ◽
Vol 73
(1)
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pp. 31-34
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2016 ◽
Vol 72
(7)
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pp. 1047-1049
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2021 ◽
Vol 77
(11)
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