A two-dimensional hydrogen-bonded water layer in the structure of a cobalt(III) cubane complex
2014 ◽
Vol 70
(2)
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pp. 198-201
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Keyword(s):
A tetranuclear CoIIIoxide complex with cubane topology, tetrakis(2,2′-bipyridine-κ2N,N′)di-μ2-carbonato-κ4O:O′-tetra-μ3-oxido-tetracobalt(III) pentadecahydrate, [Co4(CO3)2O4(C10H8N2)4]·15H2O, with an unbounded hydrogen-bonded water layer, has been synthesized by reaction of CoCO3and 2,2′-bipyridine. The solvent water molecules form a hydrogen-bonded net with tetrameric and pentameric water clusters as subunits. The Co4O4cubane-like cores are sandwiched between the water layers, which are further stacked into a three-dimensional metallo-supramolecular network.
2014 ◽
Vol 70
(11)
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pp. 1083-1087
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Keyword(s):
2014 ◽
Vol 70
(3)
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pp. 315-319
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2007 ◽
Vol 63
(11)
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pp. m2818-m2818
Phosphonopropionic acid as a building block in supramolecular chemistry: salts with organic diamines
2003 ◽
Vol 59
(2)
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pp. 248-262
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2018 ◽
Vol 74
(4)
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pp. 504-512
2014 ◽
Vol 70
(2)
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pp. 189-193
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2013 ◽
Vol 69
(12)
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pp. 1545-1548
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2006 ◽
Vol 62
(7)
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pp. o2797-o2799
Keyword(s):
2013 ◽
Vol 69
(8)
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pp. 829-832
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