Crystal structure and Hirshfeld surface analysis of trans-2,5-dimethylpiperazine-1,4-diium tetrachloridocobaltate(II)
2021 ◽
Vol 77
(4)
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pp. 424-427
Keyword(s):
In the title molecular salt, (C6H16N2)[CoCl4], the complete dication is generated by crystallographic inversion symmetry and the piperazine ring adopts a chair conformation with the pendant methyl groups in equatorial orientations. The complete dianion is generated by crystallographic twofold symmetry. In the crystal, the (C6H16N2)2+ and [CoCl4]2− ions are linked by N—H...Cl and C—H...Cl hydrogen bonds, thereby forming a two-dimensional supramolecular network. The Hirshfeld surface analysis and fingerprint plots reveal that the largest contributions to the crystal stability come from H...Cl/Cl...H (68.4%) and H...H (27.4%) contacts.
2016 ◽
Vol 72
(4)
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pp. 593-596
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2018 ◽
Vol 74
(7)
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pp. 931-934
2021 ◽
Vol 77
(1)
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pp. 1-4
2020 ◽
Vol 76
(4)
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pp. 576-580
Keyword(s):
2019 ◽
Vol 75
(9)
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pp. 1297-1300
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2020 ◽
Vol 76
(5)
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pp. 728-731
2020 ◽
Vol 76
(6)
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pp. 794-797
2021 ◽
Vol 77
(2)
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pp. 86-90
2018 ◽
Vol 74
(9)
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pp. 1211-1214
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