Tetrakis[μ2-5-nitro-2-(phenylsulfanyl)benzoato-κ2
O:O′]bis[(acetonitrile-κN)copper(II)]
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The title compound, [Cu2(μ2-O2CC12H8NO2S)4(CH3CN)2], consists of a dinuclear and centrosymmetric complex based on two CuII atoms coordinated by four 5-nitro-2-phenylsulfanyl-benzoate anions and two acetonitrile ligands. Each benzoate anion acts as a bis-monodentate ligand while each acetonitrile acts as a monodentate ligand, leading to a square-pyramidal NO4 coordination environment for each CuII atom with the acetonitrile N atom at the apex. The intramolecular Cu...Cu distance in the dimer is 2.6478 (3) Å. The cohesion of the crystal structure is ensured by (phenyl)C—H...O(nitro) hydrogen bonds and (phenyl)C—H...π interactions.
2015 ◽
Vol 71
(5)
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pp. 452-454
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2015 ◽
Vol 71
(2)
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pp. 192-194
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2009 ◽
Vol 65
(6)
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pp. m673-m673
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2015 ◽
Vol 71
(1)
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pp. 8-11
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2015 ◽
Vol 71
(9)
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pp. o636-o636
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2009 ◽
Vol 65
(6)
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pp. o1310-o1310
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2016 ◽
Vol 72
(1)
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pp. 60-62
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