Dichlorido(pyridine-κN)[2,3,5,6-tetrakis(pyridin-2-yl)pyrazine-κ3
N
2,N
1,N
6]nickel(II)
Keyword(s):
In the title complex, [NiCl2(C5H5N)(C24H16N6)], the NiII ion is six-coordinated in a distorted octahedral coordination environment defined by three N atoms of the tridentate 2,3,5,6-tetra-2-pyridylpyrazine ligand, one N atom of the pyridine ligand and two Cl− anions, with the latter being mutually trans. The complex is disposed about a twofold rotation axis along the a axis. The complex molecules are connected in the crystal via C—H...Cl, C—H...N and π–π [closest inter-centroid separation = 3.7446 (14) Å between pyridyl rings].
2016 ◽
Vol 72
(10)
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pp. 1383-1385
2017 ◽
Vol 73
(9)
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pp. 1302-1304
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2012 ◽
Vol 68
(6)
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pp. m785-m785
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2012 ◽
Vol 68
(6)
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pp. m857-m857
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2009 ◽
Vol 65
(6)
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pp. m618-m618
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2015 ◽
Vol 71
(2)
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pp. 195-198
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2012 ◽
Vol 68
(8)
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pp. m1121-m1121
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