catena-Poly[[bis(quinolin-8-amine-κ2
N,N′)cadmium(II)]-μ-cyanido-κ2
N:C-[dicyanidonickel(II)]-μ-cyanido-κ2
C:N]
Keyword(s):
In the title compound, [CdNi(C9H8N2)2(CN)4] n , the Cd and Ni atoms both lie on centres of inversion in space group P21/c. The Cd atom is coordinated by two bidentate quinolin-8-amine ligands and by the N atoms of two cyano ligands, while the square planar Ni atom is coordinated by the C atoms of four cyano ligands. These units form a one-dimensional coordination polymer containing an (–NC—Ni—CN—Cd–) n backbone, and the coordination polymer chains are linked into a three-dimensional array by a combination of N—H...N and C—H...N hydrogen bonds, augmented by a π–π stacking interaction.
2014 ◽
Vol 70
(7)
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pp. 702-706
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2014 ◽
Vol 70
(8)
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pp. m298-m299
2012 ◽
Vol 68
(7)
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pp. m169-m172
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Keyword(s):
2014 ◽
Vol 70
(4)
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pp. 359-363
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2007 ◽
Vol 63
(11)
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pp. m2780-m2780
Keyword(s):
2012 ◽
Vol 68
(8)
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pp. m1131-m1131
Keyword(s):
2013 ◽
Vol 69
(10)
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pp. 1140-1143
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2007 ◽
Vol 63
(11)
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pp. m2705-m2705
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Keyword(s):
2012 ◽
Vol 68
(2)
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pp. m41-m44
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