ABSTRACTA vector network analyzer combined with an open ended coaxial probe provides a way to make non-destructive measurements of complex permittivity. These measurements can be made on both solids and liquids.Many authors have done work on using an open ended coaxial line for making these measurements[1][2][3]. They have presented different techniques for modelling the coaxial probe. This paper does not focus on the area of modelling, but deals instead with the use of a vector network analyzer and coaxial probe in making measurements. To enhance measurement accuracy, the technique described adapts a calibration technique currently in use in vector network analysis.An HP 8720B vector network analyzer was used for the development and measurements presented in this paper.