Towards prospective life cycle assessment: Single wall carbon nanotubes for lithium-ion batteries

Author(s):  
Ben A. Wender ◽  
Thomas P. Seager
ATZ worldwide ◽  
2020 ◽  
Vol 122 (4) ◽  
pp. 56-59
Author(s):  
Andreas Bärmann ◽  
Lucia Bäuml ◽  
Alexander Martin

2012 ◽  
Vol 1439 ◽  
pp. 157-162 ◽  
Author(s):  
Matthew J. Ganter ◽  
Roberta A. DiLeo ◽  
Amanda Doucett ◽  
Christopher M. Schauerman ◽  
Reginald E. Rogers ◽  
...  

ABSTRACTSingle wall carbon nanotubes (SWCNTs) were incorporated into lithium ion battery anodes as conductive additives in mesocarbon microbead (MCMB) composites and as a free-standing support for silicon active materials. In the traditional MCMB composite, 0.5% w/w SWCNTs were used to replace 0.5% w/w SuperP conductive additives. The composite with 0.5% SWCNTs had nearly three times the conductivity which leads to improved electrochemical performance at higher discharge rates with a 20% increase in capacity at greater than a C/2 rate. The thermal stability and safety was measured using differential scanning calorimetry (DSC), and a 35% reduction in exothermic energy released was measured using the highly thermally conductive SWCNTs as an additive. Alternatively, free-standing SWCNT papers were coated with increasing amounts of silicon using a low pressure chemical vapor deposition technique and a silane precursor. Increasing the amount of silicon deposited led to a significant increase in specific capacity (>2000 mAh/g) and coulombic efficiency (>90%). At the highest silicon loading, the surface area of the electrode was reduced by over an order of magnitude which leads to lower solid electrolyte interface formation and improved safety as measured by DSC.


Energies ◽  
2021 ◽  
Vol 14 (17) ◽  
pp. 5555
Author(s):  
Jhuma Sadhukhan ◽  
Mark Christensen

Battery energy storage systems (BESS) are an essential component of renewable electricity infrastructure to resolve the intermittency in the availability of renewable resources. To keep the global temperature rise below 1.5 °C, renewable electricity and electrification of the majority of the sectors are a key proposition of the national and international policies and strategies. Thus, the role of BESS in achieving the climate impact mitigation target is significant. There is an unmet need for a detailed life cycle assessment (LCA) of BESS with lithium-ion batteries being the most promising one. This study conducts a rigorous and comprehensive LCA of lithium-ion batteries to demonstrate the life cycle environmental impact hotspots and ways to improve the hotspots for the sustainable development of BESS and thus, renewable electricity infrastructure. The whole system LCA of lithium-ion batteries shows a global warming potential (GWP) of 1.7, 6.7 and 8.1 kg CO2 eq kg−1 in change-oriented (consequential) and present with and without recycling credit consideration, scenarios. The GWP hotspot is the lithium-ion cathode, which is due to lithium hexafluorophosphate that is ultimately due to the resource-intensive production system of phosphorous, white, liquid. To compete against the fossil economy, the GWP of BESS must be curbed by 13 folds. To be comparable with renewable energy systems, hydroelectric, wind, biomass, geothermal and solar (4–76 g CO2 eq kWh−1), 300 folds reduction in the GWP of BESS will be necessary. The areas of improvement to lower the GWP of BESS are as follows: reducing scopes 2–3 emissions from fossil resource use in the material production processes by phosphorous recycling, increasing energy density, increasing lifespan by effective services, increasing recyclability and number of lives, waste resource acquisition for the battery components and deploying multi-faceted integrated roles of BESS. Achieving the above can be translated into an overall avoided GWP of up to 82% by 2040.


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