Effects of temperature and buffer gases on the reactions of nitric oxide with vibrationally excited ozone

1975 ◽  
Vol 11 (8) ◽  
pp. 715-715
Author(s):  
R. Gordon ◽  
M. Lin
Keyword(s):  
Nitric Oxide ◽  
Vibrationally Excited ◽  
Effects Of Temperature

Towards Vibrationally Excited Nitric Oxide Monitoring (VENOM) in a Laminar, Hypersonic Boundary Layer

2020 ◽  
Author(s):  
Zachary D. Buen ◽  
Casey Broslawski ◽  
Madeline Smotzer ◽  
Jason E. Kuszynski ◽  
Simon North ◽  
...  
Keyword(s):  
Nitric Oxide ◽  
Boundary Layer ◽  
Hypersonic Boundary Layer ◽  
Vibrationally Excited

Quenching of vibrationally excited nitric oxide by molecular oxygen and nitrogen

1975 ◽  
Vol 63 (7) ◽  
pp. 2919 ◽  
Author(s):  
R. E. Murphy ◽  
E. T. P. Lee ◽  
A. M. Hart
Keyword(s):  
Nitric Oxide ◽  
Molecular Oxygen ◽  
Vibrationally Excited

The reaction of cyanogen radicals with nitric oxide

1965 ◽  
Vol 283 (1394) ◽  
pp. 291-301 ◽  
Keyword(s):  
Nitric Oxide ◽  
Chemical Reaction ◽  
Vibrational Energy ◽  
Vibrational Excitation ◽  
Resonance Energy ◽  
Ultra Violet ◽  
Vibrationally Excited ◽  
Near Resonance ◽  
Continuous Absorption ◽  
Unstable Compound

Vibrational energy transfer and a chemical reaction between nitric oxide and the cyanogen radical have been studied by flash photolysing cyanogen and cyanogen bromide in the presence of nitric oxide. The product of the chemical reaction is, at least in part, the unstable compound nitrosyl cyanide NOCN and the rate constant is 2 x 10 12 ml. mole -1 s -1 or 1 x 10 17 ml. mole -2 s -1 with nitrogen as third body. The compound has a continuous absorption in the ultra-violet and yields vibrationally excited nitric oxide on photolysis. Vibrationally excited cyanogen radicals produced by means of electronic excitation of the radical produce vibrational excitation of the nitric oxide through near resonance energy exchange. Vibrational equilibrium is reached by nitric oxide through further resonance exchanges: CN + NO → NOCN, NOCN + hv → N O ( v > 0) + CN, NO ( v = 0) + CN ( v = n ) → NO ( v = 1) + CN ( v = n – 1 ) , NO ( v = 1) + CN ( v = m ) → NO ( v = 2) + CN ( v = m –1 ), 2NO { v = 1) ⇌ NO ( v = 2) + NO ( v = 0), NO ( v = 2) +NO ( v = 1) ⇌ NO ( v = 3) + NO { v = 0), etc.

scholarly journals Temperature perturbation related to the invisible ink vibrationally excited nitric oxide monitoring (VENOM) technique: a simulation study

2019 ◽  
Vol 58 (10) ◽  
pp. 2702 ◽  
Author(s):  
Joshua D. Winner ◽  
Feng Pan ◽  
Madison H. McIlvoy ◽  
Rodney D. W. Bowersox ◽  
Simon W. North
Keyword(s):  
Nitric Oxide ◽  
Simulation Study ◽  
Temperature Perturbation ◽  
Vibrationally Excited ◽  
The Invisible

Energy disequilibrium in the flash photolysis of NO 2

1973 ◽  
Vol 334 (1599) ◽  
pp. 553-568 ◽  
Keyword(s):  
Nitric Oxide ◽  
Flash Photolysis ◽  
Vibrational Energy ◽  
Dissociation Limit ◽  
Primary Process ◽  
Transfer Energy ◽  
Vibrationally Excited ◽  
Absolute Concentrations ◽  
The Absolute ◽  
Excited Oxygen

From measurements of the absolute concentrations of vibrationally excited oxygen produced in levels v" = 4 to v" = 13, it is concluded that ca . 20 % of the exothermicity of the reaction O( 3 P) + NO 2 → NO + O + 2 ( v" ≤11) (1) appears initially as vibrational energy in oxygen. Vibrationally excited nitric oxide ( v" = 1, 2) is also observed and may be produced in this reaction or in the primary process NO 2 + hv → NO ( v" ≤ 2) + O( 3 P). More highly excited oxygen ( v" ≤ 15), with energy exceeding the exothermicity of the reaction, is produced in reaction (1) when the NO 2 is first excited by radiation above the dissociation limit near 400 nm. The excited NO 2 thus produced can also transfer energy to nitric oxide. NO 2 * + NO( v" = 0) → NO 2 + NO( v" = 1).

The reaction of nitric oxide with vibrationally excited ozone. II

1976 ◽  
Vol 64 (3) ◽  
pp. 1058-1064 ◽  
Author(s):  
Robert J. Gordon ◽  
M. C. Lin
Keyword(s):  
Nitric Oxide ◽  
Vibrationally Excited

Vibrational relaxation of nitric oxide and carbon monoxide, studied by kinetic spectroscopy

1962 ◽  
Vol 269 (1337) ◽  
pp. 180-187 ◽  
Keyword(s):  
Nitric Oxide ◽  
Carbon Monoxide ◽  
Vibrational Relaxation ◽  
Vibrationally Excited ◽  
Kinetic Spectroscopy ◽  
Excited Molecules

Vibrationally excited carbon monoxide was produced by flashing mixtures of nitric oxide, carbon monoxide and nitrogen. The rate of formation and decay of the vibrationally excited molecules was interpreted by means of the processes: NO ( X 2 I I , υ = 0 ) + h v → NO ( A 2 ∑ + , υ = 0 , 1 , 2 ) , NO ( A 2 ∑ + , υ = 0 , 1 , 2 ) + M →→ NO ( X 2 I I , υ = 1 ) + M , NO ( A 2 ∑ + , υ = 0 , 1 , 2 ) →→ NO ( X 2 I I ) , υ = 1 ) + h v , NO ( X 2 I I , υ = 1 ) + CO X 1 ∑ + ( υ = 0 ) → ← NO ( X 2 I I , υ = 0 ) + CO ( X 1 ∑ + , υ = 1 ) , CO ( X 1 ∑ + , υ = 1 ) + N 2 X 1 ∑ V + ( υ = 0 ) → ← CO ( X 1 ∑ + , υ = 0 ) + N 2 ( X 1 ∑ V + , υ = 1 ) , NO ( X 2 I I , υ = 1 ) + NO X 2 I I ( υ = 0 ) → 2 NO ( X 2 I I , υ = 0 ) .

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