Inversion of Chromophoric Dissolved Organic Matter From EO-1 Hyperion Imagery for Turbid Estuarine and Coastal Waters

2013 ◽  
Vol 51 (6) ◽  
pp. 3286-3298 ◽  
Author(s):  
Weining Zhu ◽  
Qian Yu

The significant implication of chromophoric dissolved organic matter (CDOM) for water quality and biogeochemical cycle leads to an increasing need of CDOM monitoring in coastal regions. Current ocean-color algorithms are mostly limited to open-sea water and have high uncertainty when directly applied to turbid coastal waters. This paper presents a semianalytical algorithm, quasi-analytical CDOM algorithm (QAA-CDOM), to invert CDOM absorption from Earth Observing-1 (EO-1) Hyperion satellite images. This algorithm was developed from a widely used ocean-color algorithm QAA and our earlier extension of QAA. The main goal is to improve the algorithm performance for a wide range of water conditions, particularly turbid waters in estuarine and coastal regions. The algorithm development, calibration, and validation were based on our intensive high-resolution underwater measurements, International Ocean Color Coordinating Group synthetic data, and global National Aeronautics and Space Administration Bio-Optical Marine Algorithm Data Set data. The result shows that retrieved CDOM absorption achieved accuracy (root mean square error (RMSE) = 0.115 m-1andR2= 0.73) in the Atchafalaya River plume area. QAA-CDOM is also evaluated for scenarios in three additional study sites, namely, the Mississippi River, Amazon River, and Moreton Bay, whereag(440) was in the wide range of 0.01-15 m-1. It resulted in expected CDOM distribution patterns along the river salinity gradient. This study improves the high-resolution observation of CDOM dynamics in river-dominated coastal margins and other coastal environments for the study of land-ocean interactive processes.

2018 ◽  
Vol 2018 ◽  
pp. 1-7 ◽  
Author(s):  
Svetlana Patsaeva ◽  
Daria Khundzhua ◽  
Oleg A. Trubetskoj ◽  
Olga E. Trubetskaya

Advanced fluorescence analysis within the wide range of excitation wavelengths from 230 to 510 nm accompanied with chromatography was used to study natural chromophoric dissolved organic matter (CDOM) from three freshwater Karelian lakes. The influence of excitation wavelength (λex) on fluorescence quantum yield and emission maximum position was determined. The CDOM fluorescence quantum yield has reached a minimum at λex∼270–280 nm and a maximum at λex∼340–360 nm. It was monotonously decreasing after 370 nm towards longer excitation wavelengths. Analytical reversed-phase high-performance liquid chromatography with multiwavelength fluorescence detector characterized distribution of fluorophores between hydrophilic/hydrophobic CDOM parts. This technique revealed “hidden” protein-like fluorophores for some CDOM fractions, in spite of the absence of protein-like fluorescence in the initial CDOM samples. The humic-like fluorescence was documented for all hydrophilic and hydrophobic CDOM chromatographic peaks, and its intensity was decreasing along with peaks’ hydrophobicity. On contrary, the protein-like fluorescence was found only in the hydrophobic peaks, and its intensity was increasing along with peaks’ hydrophobicity. This work provides new data on the CDOM optical properties consistent with the formation of supramolecular assemblies controlled by association of low-molecular size components. In addition, these data are very useful for understanding the CDOM function in the environment.


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