scholarly journals High Proton Conductive Sulfonated Graph Copolyimide Membranes Containing Chemically Stable Naphthalene Moieties

2017 ◽  
Vol 12 (1) ◽  
Author(s):  
K. Yamazaki ◽  
M. Tanaka ◽  
H. Kawakami
Keyword(s):  
Proton Conductivity ◽  
Oxygen Permeability ◽  
Main Chain ◽  
Gas Permeability ◽  
The Novel ◽  
High Proton Conductivity ◽  
Gas Barrier ◽  
Polymer Main Chain ◽  
High Proton ◽  
Potential Applications

Syntheses, proton conductivity, gas permeability properties, and membrane stabilities of novel sulfonated graft copolyimides were investigated. The sulfonated graft copolyimide membrane showed significantly high proton conductivity (0.96 S/cm at 90°C and 98%RH, more than 6 times that of Nafion), suggesting that the protons in the sulfonated graft copolyimide membranes were efficiently transported. The oxidative stability of the novel sulfonated graft copolyimide was higher than that of the conventional graft copolyimide because of their polymer structures containing chemically stable naphthalene moieties and non–sulfonated polymer main–chain. Furthermore, the oxygen permeability of the membrane was approximately one–fourth the value of Nafion and had a very excellent gas barrier property. We demonstrated that the graft copolymer membrane could realize high proton conductivity and low gas permeability to have potential applications for use in fuel cells.

A sulfonated polybenzophenone/polyimide copolymer as a novel proton exchange membrane

RSC Advances ◽  
2015 ◽  
Vol 5 (62) ◽  
pp. 50082-50086 ◽  
Author(s):  
Takahiro Miyahara ◽  
Junpei Miyake ◽  
Soichi Matsuno ◽  
Masahiro Watanabe ◽  
Kenji Miyatake
Keyword(s):  
Fuel Cell ◽  
Block Copolymer ◽  
Proton Conductivity ◽  
Proton Exchange Membrane ◽  
Gas Permeability ◽  
Proton Exchange ◽  
High Proton Conductivity ◽  
High Proton ◽  
Exchange Membrane

A sulfonated polybenzophenone/polyimide block copolymer membrane exhibited high proton conductivity, good dimensional and mechanical stabilities, and low gas permeability, which are attractive for fuel cell applications.

High proton conductivity in a nickel(ii) complex and its hybrid membrane

2019 ◽  
Vol 48 (6) ◽  
pp. 2190-2196 ◽  
Author(s):  
Shuai-Liang Yang ◽  
Yue-Ying Yuan ◽  
Fei Ren ◽  
Chen-Xi Zhang ◽  
Qing-Lun Wang
Keyword(s):  
Hydrogen Bond ◽  
Proton Conductivity ◽  
Hybrid Membrane ◽  
Water Molecules ◽  
Hybrid Membranes ◽  
High Proton Conductivity ◽  
High Proton ◽  
Hydrogen Bond Networks

A novel 2D nickel(ii) complex (1) has been successfully synthesized using a 2,2′-bipyridyl, polycarboxylsulfonate ligand H4SBTC and Ni2+ ions. Owing to the presence of abundant water molecules, hydrogen bond networks and other protons, 1 and its hybrid membranes demonstrate high proton conductivity.

Synthesis and characterization of chemically stable sulfonated copoly(triazole imide)s with high proton conductivity

2019 ◽  
Vol 59 (11) ◽  
pp. 2279-2289 ◽  
Author(s):  
Asheesh Singh ◽  
Anaparthi G. Kumar ◽  
Sayantani Saha ◽  
Rajdeep Mukherjee ◽  
Soumendu Bisoi ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Synthesis And Characterization ◽  
High Proton Conductivity ◽  
High Proton

Cations mediating proton conductivity in an oxalate based microporous coordination polymer

2019 ◽  
Vol 43 (1) ◽  
pp. 24-27 ◽  
Author(s):  
Xing Meng ◽  
Hai-Ning Wang ◽  
Xiao-Kun Wang ◽  
Long-Zhang Dong ◽  
Yan-Hong Zou
Keyword(s):  
Structural Change ◽  
Relative Humidity ◽  
Coordination Polymer ◽  
Proton Conductivity ◽  
Cation Substitution ◽  
High Proton Conductivity ◽  
High Proton

Through cation substitution in a zirconium based coordination polymer, an isostructural framework 1@NH4+ has been prepared without any apparent structural change. The proton conductivity of 1@NH4+ is successfully improved. It exhibits high proton conductivity (1.39 × 10−2 S cm−1) at 98% relative humidity and 60 °C.

Metal–organic frameworks derived from a semi-rigid anthracene-based ligand and sulfonates: proton conductivity and dye degradation studies

CrystEngComm ◽  
2021 ◽  
Author(s):  
Aurobinda Mohanty ◽  
Udai P. Singh ◽  
Arijit Ghorai ◽  
Susanta Banerjee ◽  
R. J. Butcher
Keyword(s):  
Methylene Blue ◽  
Relative Humidity ◽  
Proton Conductivity ◽  
Dye Degradation ◽  
Metal Organic Frameworks ◽  
High Proton Conductivity ◽  
Methylene Blue Degradation ◽  
High Proton ◽  
Metal Organic ◽  
Degradation Studies

The MOFs were constructed by ligand AHP and sulfonate analogues. MOF4 exhibits a high proton conductivity of 1.95 × 10−3 S cm−1 at 95 °C and 98% relative humidity. MOFs 1–5 also serve as photocatalysts for methylene blue degradation.

Simple and universal synthesis of sulfonated porous organic polymers with high proton conductivity

2020 ◽  
Vol 4 (8) ◽  
pp. 2339-2345 ◽  
Author(s):  
Zhongping Li ◽  
Yuze Yao ◽  
Dongjin Wang ◽  
Md. Mahmudul Hasan ◽  
Athchaya Suwansoontorn ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Organic Polymers ◽  
High Proton Conductivity ◽  
Porous Organic Polymers ◽  
Conductive Materials ◽  
High Proton

By using a simple and universal process, we successfully synthesized various sulfonated porous organic polymers with high proton conductivity, and therefore this strategy could evolve structural designs for high proton-conductive materials.

scholarly journals Polyimide‐PEG Segmented Block Copolymer Membranes with High Proton Conductivity by Improving Bicontinuous Nanostructure of Ionic Liquid‐Doped Films

2019 ◽  
Vol 220 (9) ◽  
pp. 1900006
Author(s):  
Euntaek Woo ◽  
Elyse Coletta ◽  
Alexander Holm ◽  
Jaewan Mun ◽  
Michael F. Toney ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Block Copolymer ◽  
Proton Conductivity ◽  
High Proton Conductivity ◽  
High Proton
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