Assessment of Sorbent Reactivation by Water Hydration for Fluidized Bed Combustion Application

Author(s):  
Fabio Montagnaro ◽  
Piero Salatino ◽  
Fabrizio Scala ◽  
Yinghai Wu ◽  
Edward Anthony ◽  
...  

Disposal of FBC solid residues currently represents one of the major issues in FBC design and operation, and contributes significantly to FBC operating cost. This issue has triggered research activities on the enhancement of sorbent utilization for in-situ sulfur uptake. The present study addresses the effectiveness of the reactivation by liquid water hydration of FB spent sorbents. Two materials are considered in the study, namely bottom ash from the operation of a full-scale utility FB boiler and the raw commercial limestone used in the same boiler. Hydration-reactivation tests were carried out at temperatures of 40°C and 80°C and for curing times ranging from 15min to 2d, depending on the sample. The influence of hydration conditions on the enhancement of sulfur utilization has been assessed. A combination of methods has been used to characterize the properties of liquid water-hydrated materials.

2005 ◽  
Vol 128 (2) ◽  
pp. 90-98 ◽  
Author(s):  
Fabio Montagnaro ◽  
Piero Salatino ◽  
Fabrizio Scala ◽  
Yinghai Wu ◽  
Edward J. Anthony ◽  
...  

Disposal of fluidized bed combustion (FBC) solid residues currently represents one of the major issues in FBC design and operation, and contributes significantly to its operating cost. This issue has triggered research activities on the enhancement of sorbent utilization for in situ sulfur removal. The present study addresses the effectiveness of the reactivation by liquid water hydration of FB spent sorbents. Two materials are considered in the study, namely the bottom ash from the operation of a full-scale utility FB boiler and the raw commercial limestone used in the same boiler. Hydration-reactivation tests were carried out at temperatures of 40°C and 80°C and for curing times ranging from 15minutes to 2d, depending on the sample. The influence of hydration conditions on the enhancement of sulfur utilization has been assessed. A combination of methods has been used to characterize the properties of liquid water-hydrated materials.


2019 ◽  
Vol 23 (Suppl. 5) ◽  
pp. 1637-1653
Author(s):  
Borislav Grubor ◽  
Dragoljub Dakic ◽  
Stevan Nemoda ◽  
Milica Mladenovic ◽  
Milijana Paprika ◽  
...  

The paper gives a review of the most important results of extensive targeted fundamental research program on fluidized bed combustion in the Laboratory for Thermal Engineering and Energy of the VINCA Institute of Nuclear Sciences. The paper presents a detailed overview of research activities from the beginning in the second half of the 1970'' up to present days. Starting with the motives for initiating the investigations in this field, the paper highlights various phases of research and points out the main results of all research activities, not only the ones that are focused in this paper. Targeted fundamental research topics that are overviewed in this paper are heat and mass transfer, coal particle fragmentation, char particle combustion, sulfur self-retention by coal ash itself, as well as circulating fluidized bed modeling.


2020 ◽  
Vol 34 ◽  
pp. 72-77
Author(s):  
Tobi Stephen Osholana ◽  
Mbuso Kingdom Dludlu ◽  
Bilainu Oboirien ◽  
Rotimi Sadiku

Author(s):  
Y. Wu ◽  
J.-P. Charland ◽  
E. J. Anthony ◽  
L. Jia

Six different fly ashes from commercial-scale circulating fluidized bed combustion (CFBC) boilers and the carbon-free residues of these ashes were hydrated with liquid water or steam to determine whether hydration could improve sorbent utilization in these samples under fluidized bed combustion conditions. After hydration, for two fly ashes (FA1 and FA6) and three carbon-free samples (FA2-A, FA3-A and FA6-A), the capacity for taking up SO2 showed limited or medium improvement; however, hydration was evidently ineffective in reactivating the remaining samples. It is believed that the reason samples FA6 and FA6-A show a relatively high improvement in SO2 absorption capacity is that these ashes had a larger particle size than any of the other fly ashes examined here. In general, even for these “reactivatable” fly ashes, reactivation by hydration with either liquid water or steam appeared far less promising than for bed ashes, which have been shown to exhibit significant improvement in sulphur capture during re-sulphation. Hydration, whether by steam or liquid water, is not recommended for fly ash, which has a very limited residence time in the boiler due to its small particle size and instead this paper recommends alternative strategies.


2018 ◽  
Vol 36 (4) ◽  
pp. 351-360 ◽  
Author(s):  
AK Mandal ◽  
Bala Ramudu Paramkusam ◽  
OP Sinha

Though the majority of research on fly ash has proved its worth as a construction material, the utility of bottom ash is yet questionable due to its generation during the pulverized combustion process. The bottom ash produced during the fluidized bed combustion (FBC) process is attracting more attention due to the novelty of coal combustion technology. But, to establish its suitability as construction material, it is necessary to characterize it thoroughly with respect to the geotechnical as well as mineralogical points of view. For fulfilling these objectives, the present study mainly aims at characterizing the FBC bottom ash and its comparison with pulverized coal combustion (PCC) bottom ash, collected from the same origin of coal. Suitability of FBC bottom ash as a dike filter material in contrast to PCC bottom ash in replacing traditional filter material such as sand was also studied. The suitability criteria for utilization of both bottom ash and river sand as filter material on pond ash as a base material were evaluated, and both river sand and FBC bottom ash were found to be satisfactory. The study shows that FBC bottom ash is a better geo-material than PCC bottom ash, and it could be highly recommended as an alternative suitable filter material for constructing ash dikes in place of conventional sand.


Materials ◽  
2020 ◽  
Vol 13 (8) ◽  
pp. 1972
Author(s):  
Rostislav Drochytka ◽  
Magdaléna Michalčíková

This paper addresses the influence of fluidized bed combustion fly ash (FBCA) and further liquefying additives on the formation of structure and on the resulting properties of self-compacting grouts based on clay soil. In order to give the best account of the influence of individual input materials, tests were conducted on samples without the use of fluidized bed combustion fly ash. Clay soil (Cl) and cement were used as input materials, and fluidized bed combustion fly ash (10% and 30%) and a liquefying additive (sodium carbonate 0.1%) were used as an admixture. It has been experimentally determined that the use of 10% FBCA with clay soil is most suitable for achieving the optimal spillage parameter of self-compacting grout (class SF2 (660–750 mm) and class SF3 (760–850 mm)). It was also found that fluidized bed combustion fly ash and the liquefying additive have a significant influence on the formation of the structure of the self-compacting grout and, due to their presence, the compressive strength of the samples increased up to 0.5 MPa after seven days of hardening. The reaction between 0.1% of sodium carbonate and clay soil increased the electrokinetic potential, which reduced the viscosity of the self-compacting grout. Within the research work, the verification of the developed self-compacting grout in situ was also carried out.


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