On the Nonlinear Behavior of a Glass-Ceramic Seal and Its Application in Planar SOFC Systems

Author(s):  
Ba Nghiep Nguyen ◽  
Brian J. Koeppel ◽  
John S. Vetrano ◽  
Mohammad A. Khaleel

This paper studies the nonlinear behavior of a glass-ceramic seal used in planar solid oxide fuel cells (SOFCs). To this end, a viscoelastic damage model has been developed that can capture the nonlinear material response due to both progressive damage in the glass-ceramic material and viscous flow of the residual glass in this material. The model has been implemented in the MSC MARC finite element code, and its validation has been carried out using the experimental relaxation test data obtained for this material at 700°C, 750°C, and 800°C. Finally, it has been applied to the simulation of a SOFC stack under thermal cycling conditions. The areas of potential damage have been predicted.

2010 ◽  
Vol 93 (3) ◽  
pp. 830-837 ◽  
Author(s):  
Ashutosh Goel ◽  
Dilshat U. Tulyaganov ◽  
Anna Maria Ferrari ◽  
Essam R. Shaaban ◽  
Andreas Prange ◽  
...  

2004 ◽  
Vol 87 (2) ◽  
pp. 254-260 ◽  
Author(s):  
Sung-Bum Sohn ◽  
Se-Young Choi ◽  
Gyeung-Ho Kim ◽  
Hue-Sup Song ◽  
Goo-Dae Kim

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4702
Author(s):  
Roberto Spotorno ◽  
Marlena Ostrowska ◽  
Simona Delsante ◽  
Ulf Dahlmann ◽  
Paolo Piccardo

A commercially available glass-ceramic composition is applied on a ferritic stainless steel (FSS) substrate reproducing a type of interface present in solid oxide fuel cells (SOFCs) stacks. Electrochemical impedance spectroscopy (EIS) is used to study the electrical response of the assembly in the temperature range of 380–780 °C and during aging for 250 h at 780 °C. Post-experiment analyses, performed by means of X-ray diffraction (XRD), and along cross-sections by scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) analysis, highlight the microstructural changes promoted by aging conditions over time. In particular, progressive crystallization of the glass-ceramic, high temperature corrosion of the substrate and diffusion of Fe and Cr ions from the FSS substrate into the sealant influence the electrical response of the system under investigation. The electrical measurements show an increase in conductivity to 5 × 10−6 S∙cm−1, more than one order of magnitude below the maximum recommended value.


2014 ◽  
Vol 2 (6) ◽  
pp. 1834-1846 ◽  
Author(s):  
Allu Amarnath Reddy ◽  
Ashutosh Goel ◽  
Dilshat U. Tulyaganov ◽  
Mariana Sardo ◽  
Luis Mafra ◽  
...  

2014 ◽  
Vol 34 (5) ◽  
pp. 1449-1455 ◽  
Author(s):  
Allu Amarnath Reddy ◽  
Neda Eghtesadi ◽  
Dilshat U. Tulyaganov ◽  
Maria J. Pascual ◽  
Luis F. Santos ◽  
...  

2016 ◽  
Vol 328 ◽  
pp. 262-270 ◽  
Author(s):  
A.G. Sabato ◽  
G. Cempura ◽  
D. Montinaro ◽  
A. Chrysanthou ◽  
M. Salvo ◽  
...  

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