Nearly Reversible Heat Engines for Thermal Storage of Excess Electric Power

Author(s):  
Jonathan S. Levine ◽  
Klaus S. Lackner ◽  
Vijay Modi

Efficient and affordable energy storage technologies would enable greater use of electricity generation with low operating but high capital cost. Such generating plants must maximize their utilization to spread capital cost over as much output as possible. Without affordable storage capacity their penetration into the market is limited to base load. Intermittent solar and wind power, which at times are simply not available, suffer even more than baseline power plants from the lack of affordable storage technologies. With the exception of pumped hydro-storage, energy storage is too expensive, suffering from low energy density in storage and low round-trip efficiency. Low grade thermal storage with temperature differences of up to about 100°C could achieve storage densities far in excess of that in most pumped storage facilities while avoiding the costs associated with high temperature operations. Roundtrip efficiency, defined as the ratio of the electric output from a heat engine driven by stored thermal energy to the electric input used to drive a heat pump to store the thermal energy, can approach 100% as the heat pump and the heat engine both approach Carnot efficiency. This theoretical limit is independent of the temperature difference between the heat reservoirs. Roundtrip efficiencies of at least 70 to 80% are necessary for energy storage to be economically competitive with higher priced electricity sources. This high round trip efficiency implies that both the heat engine and the heat pump would have to operate at 85 to 90% of the efficiency of a reversible engine. The most promising practical engines for such high efficiency are based on the Stirling cycle. This paper discusses a variation of the Stirling cycle aimed at large, slow units optimized for high efficiency far in excess of the Curzon-Ahlborn efficiency, which results from maximizing the power of the engine. This tradeoff in favor of efficiency over power output demands extreme simplicity in design, as the size of the engine is far larger than that of conventional engines optimized for power throughput. The goal of the paper is to show that low-grade thermal energy storage could provide a viable alternative to regionally limited pumped hydro-storage as long as the design challenges explained in the paper can be overcome. Given the current lack of cost-effective, scalable energy storage systems, thermal storage technology could have a profound impact on future energy infrastructures.

Author(s):  
Richard B. Peterson ◽  
Robbie Ingram-Goble ◽  
Kevin J. Harada ◽  
Hailei Wang

In order for renewable energy to displace 20% or more of the conventional power generating base without depending on significant hot spinning reserves, reliable and cost effective energy storage will be needed at the utility scale. Developing and deploying practical energy storage at this level is a major challenge and no single technology appears to have a dominant position. Storing electrical energy by way of thermal storage at moderate-to-low temperatures has not received much attention in the past. In fact, the conventional thinking is that heat pump/heat engine mediated energy storage is too inefficient (round trip efficiency of 30% or lower) to be practical. However, an innovative and efficient storage approach is proposed in this paper by incorporating sensible heat storage in a Rankine-type heat pump/heat engine cycle to increase the round trip efficiency. Furthermore, by using a source of waste (or otherwise low-grade) heat, round trip efficiencies can be enhanced further. Currently, there appears to be no significant linkage between waste heat recovery and grid-level energy storage, although the market opportunity for each is considerable. Using the thermal approach described here, a system can be created that uses very low-grade heat in the range between 50 to 70 °C. Furthermore, conventional technology can be used to implement the system where no extreme conditions are present anywhere in the cycle. Hence, it is thought to have advantages over other energy storage concepts being developed.


2019 ◽  
Author(s):  
Karolina Matuszek ◽  
R. Vijayaraghavan ◽  
Craig Forsyth ◽  
Surianarayanan Mahadevan ◽  
Mega Kar ◽  
...  

Renewable energy has the ultimate capacity to resolve the environmental and scarcity challenges of the world’s energy supplies. However, both the utility of these sources and the economics of their implementation are strongly limited by their intermittent nature; inexpensive means of energy storage therefore needs to be part of the design. Distributed thermal energy storage is surprisingly underdeveloped in this context, in part due to the lack of advanced storage materials. Here, we describe a novel family of thermal energy storage materials based on pyrazolium cation, that operate in the 100-220°C temperature range, offering safe, inexpensive capacity, opening new pathways for high efficiency collection and storage of both solar-thermal energy, as well as excess wind power. We probe the molecular origins of the high thermal energy storage capacity of these ionic materials and demonstrate extended cycling that provides a basis for further scale up and development.


2021 ◽  
Vol 11 (4) ◽  
pp. 1390
Author(s):  
Rocío Bayón

Thermal energy storage using phase change materials (PCMs) is a research topic that has attracted much attention in recent decades [...]


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