CO2 Capture from IGCC by Low-Temperature Synthesis Gas Separation

Capture conditions for CO2 vary substantially between industrial point sources. Depending on CO2 fraction and pressure level, different capture technologies will be required for cost- and energy-efficient decarbonisation. For decarbonisation of shifted synthesis gas from coal gasification, several studies have identified low-temperature CO2 capture by condensation and phase separation as an energy- and cost-efficient option. In the present work, a process design is proposed for low-temperature CO2 capture from an Integrated Gasification Combined Cycle (IGCC) power plant. Steady-state simulations were carried out and the performance of the overall process, as well as major process components, were investigated. For the baseline capture unit layout, delivering high-pressure CO2 at 150 bar, the net specific power requirement was estimated to 273 kJe/kgCO2, and an 85% CO2 capture ratio was obtained. The impact of 12 different process parameters was studied in a sensitivity analysis, the results of which show that compressor and expander efficiencies, as well as synthesis gas separation temperature, have the highest impact on power requirements. Modifying the process to producing cold liquid CO2 for ship transport resulted in 16% increase in net power requirements and is well suited for capturing CO2 for ship transport.

A Modeling and Analysis Framework for Integrated Energy Systems Exposed to Climate Change-Induced NaTech Accidental Scenarios

This paper proposes a novel framework for the analysis of integrated energy systems (IESs) exposed to both stochastic failures and “shock” climate-induced failures, such as those characterizing NaTech accidental scenarios. With such a framework, standard centralized systems (CS), IES with distributed generation (IES-DG) and IES with bidirectional energy conversion (IES+P2G) enabled by power-to-gas (P2G) facilities can be analyzed. The framework embeds the model of each single production plant in an integrated power-flow model and then couples it with a stochastic failures model and a climate-induced failure model, which simulates the occurrence of extreme weather events (e.g., flooding) driven by climate change. To illustrate how to operationalize the analysis in practice, a case study of a realistic IES has been considered that comprises two combined cycle gas turbine plants (CCGT), a nuclear power plant (NPP), two wind farms (WF), a solar photovoltaicS (PV) field and a power-to-gas station (P2G). Results suggest that the IESs are resilient to climate-induced failures.

Determination of average relative capital investment of 30–125 MW combined-cycle plants commissioned at Russian thermal power plants in 2015–2020. Comparative analysis with data obtained in 2010–2014

The present work examines average relative capital investment and fuel consumption for electric and thermal energy supply of the combined-cycle plants having 30–125 MW gas turbines commissioned at Russian thermal power plants in 2015–2020. In this work, we used general calculation methods of average relative capital investments and fuel consumption for the electrical and thermal energy supply using power equipment of thermal power plants. To assess the scope of commissioning gas turbines incorporated into the combined-cycle plants, they were classified into three groups by electrical power: 30–59 MW, 60–99 MW and 100–125 MW. The scope of commissioning gas turbines incorporated into the Russian combined-cycle plants in 2015–2020 was analysed. The average relative capital invest-ment in combined-cycle plants having 30–125 MW gas turbines, as well as the average specific fuel consumption for the electrical and thermal energy supply, were calculated. The calculations were carried out for each part of combined-cycle plants integrated into thermal power plants with a breakdown by seven Unified Energy Systems of Russia. The quantita-tive commissioning of gas turbines is compared for the periods from 2010 to the economic crisis of 2014 and after 2014 to the present: a ~2.5-fold decrease is demonstrated. A preliminary evaluation of the increase in average relative capital investment in combined-cycle plants having gas turbines of the same electric power was performed.

Exergy Analysis of Alternative Configurations of Biomass-Based Light Olefin Production System with a Combined-Cycle Scheme via Methanol Intermediate

Thermodynamic performance of three conceptual systems for biomass-derived olefin production with electricity cogeneration was studied and compared via exergy analysis at the levels of system, subsystem and operation unit. The base case was composed of the subsystems of gasification, raw fuel gas adjustment, methanol/light olefin synthesis and steam & power generation, etc. The power case and fuel case were designed as the combustion of a fraction of gasification gas to increase power generation and the recycle of a fraction of synthesis tail gas to increase olefin production, respectively. It was found that the subsystems of gasification and steam & power generation contribute ca. 80% of overall exergy destruction for each case, of which gasifier and combustor are the main exergy destruction sources, due to the corresponding chemical exergy degrading of biomass and fuel gas. The low efficiency of 33.1% for the power case could be attributed to the significant irreversibility of the combustor, economizer, and condenser in the combined-cycle subsystem. The effect of the tail gas recycle ratio, moisture content of feedstock, and biomass type was also investigated to enhance system exergy performance, which could be achieved by high recycle ratio, using dry biomass and the feedstock with high carbon content. High system efficiency of 38.9% was obtained when oil palm shell was used, which was 31.7% for rice husk due to its low carbon content.

Exergetic Analysis of a Natural Gas Combined-Cycle Power Plant with a Molten Carbonate Fuel Cell for Carbon Capture

This study aims to propose the repowering of an existing Italian natural-gas fired combined cycle power plant through the integration of Molten Carbonate Fuel Cells (MCFC) downstream of the gas turbine for CO2 capture and to pursuit an exergetic analysis of the two schemes. The flue gases of the turbine are used to feed the cathode of the MCFC, where CO2 is captured and transported to the anode while generating electric power. The retrofitted plant produces 787.454 MW, in particular, 435.29 MW from the gas turbine, 248.9 MW from the steam cycle, and 135.283 MW from the MCFC. Around 42.4% of the exergy destruction has been obtained, the majority belonging to the combustion chamber and, in minor percentages, to the gas turbine and the MCFC. The overall net plant efficiency and net exergy efficiency are estimated to be around 55.34 and 53.34%, respectively. Finally, the specific CO2 emission is around 66.67 kg/MWh, with around 2 million tons of carbon dioxide sequestrated.