Application of Advanced Model of Zr-Based Cladding Oxidation in Steam-Oxygen-Nitrogen Gas Mixtures to Separate Effects Tests and Integral Experiments
During postulated design-basis or beyond-design-basis accident at nuclear power plant with PWR or BWR, the high temperature oxidation of Zr-based fuel claddings in H2O-O2-N2 gas atmosphere could take place. Recent experimental observations showed that the oxidation of those claddings in the air (or, more generally, in oxygen-nitrogen and steam-nitrogen mixtures) behaves in much more aggressive way (linear or enhanced parabolic kinetics) compared to oxidation in pure steam (standard parabolic kinetics). This is why an advanced model of Zr-based cladding oxidation was developed. For calculations of cladding oxidation in oxygen-nitrogen and steam-nitrogen mixtures, the effective oxygen diffusion coefficient in ZrO2+ZrN layer formed in cladding is used. The diffusion coefficient enhancement factor depends on ZrN content in ZrO2+ZrN layer. A numerical scheme was realized to determine ZrO2+ZrN/α-Zr(O) and α-Zr(O)/β-Zr layers boundaries relocation and layers transformations in claddings. The model was implemented to the SOCRAT best estimate computer modeling code. The SOCRAT code with advanced model of oxidation was successfully used for calculations of separate effects tests and air ingress integral experiments QUENCH-10, QUENCH-16 and PARAMETER-SF4.