Mechanical Recycling of Low-Density Polyethylene/Carbon Nanotube Composites and its Effect on Material Properties

Author(s):  
Felicia Stan ◽  
Nicoleta-Violeta Stanciu ◽  
Catalin Fetecau ◽  
Ionut-Laurentiu Sandu

Abstract In this paper, the impact of recycling and remanufacturing on the behavior of low-density polyethylene/multi-walled carbon nanotube (LDPE/MWCNT) composites is investigated. LDPE/MWCNT composites with 0.1–5 wt.%, previously manufactured by injection molding, were mechanically recycled and remanufactured by injection molding and 3D filament extrusion, and the rheological, electrical, and mechanical properties were analyzed and compared with those of virgin composites under the same conditions. Experimental results demonstrate that the recycled LDPE/MWCNT composites have similar rheological, electrical, and mechanical properties to virgin composites, if not better. Therefore, the recycled LDPE/MWCNT composites have a great potential for being used in engineering applications, while reducing the environmental impact.

2019 ◽  
Vol 141 (9) ◽  
Author(s):  
Felicia Stan ◽  
Nicoleta-Violeta Stanciu ◽  
Catalin Fetecau ◽  
Ionut-Laurentiu Sandu

In this paper, the impact of recycling and remanufacturing on the behavior of low-density polyethylene/multi-walled carbon nanotube (LDPE/MWCNT) composites is investigated. LDPE/MWCNT composites with 0.1–5 wt%, previously manufactured by injection molding, were mechanically recycled and remanufactured by injection molding and 3D filament extrusion, and the rheological, electrical, and mechanical properties were analyzed and compared with those of virgin composites under the same conditions. Experimental results demonstrate that the recycled LDPE/MWCNT composites have similar rheological, electrical, and mechanical properties as that of virgin composites, if not better. Therefore, the recycled LDPE/MWCNT composites have a great potential for being used in engineering applications, while reducing the environmental impact.


2016 ◽  
Author(s):  
Felicia Stan ◽  
Laurentiu Ionut Sandu ◽  
Catalin Fetecau ◽  
Razvan Train Rosculet

In the near future, carbon nanotubes containing plastic parts are likely to enter the environment in large quantities and, due to their resistance to degradation, the environmental impact may be even more important than that of similarly shaped plastic products. Thus, there is an immediate need to examine and understand the effect of recycling on the properties of polymer/carbon nanotube composites in order to develop sustainable recycling technologies. In this paper, polypropylene filled with different levels of multi-walled carbon nanotubes (MWCNTs) manufactured by injection molding was closed-loop recycled in order to investigate the effect of recycling and reprocessing on its rheological, electrical and mechanical properties. Preliminary results show that the PP/MWCNT composites keep the flow performance after mechanical recycling. Moreover, the stress and strain at break increase after one reprocessing cycle (mechanical recycling coupled with injection molding) whereas no statistically significant changes in electrical conductivity, Young modulus and tensile strength of the PP/MWCNT composites filled with 1, 3 and 5 wt.% were observed.


2014 ◽  
Vol 979 ◽  
pp. 107-110
Author(s):  
Samor Boonphan ◽  
Pisith Singjai

Step-heating (single-and four-step heating) was used in the melt-mixing preparation of linear low density polyethylene (LLDPE)/multi-walled carbon nanotube (MWNT) composites. The MWNT in the composites were used at volume fractions of 0, 1, 3, 5, and 10 vol% (four-step heating), and 0, 1, 3, and 5 vol% (single-step heating). The effects of the heating steps on the microstructure of the LLDPE/MWNT composites were studied. An ultimate tensile testing machine and an impact testing machine were used to characterize the mechanical properties of the composites. The sample prepared using four-step heating had a lower porosity than the sample prepared using single-step heating. The sample with 3 vol% MWNT that was prepared using four-step heating had tensile strength, elastic modulus, and impact strength values that were higher than those of the other samples.


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