Ene reaction mechanisms. 3. Intermolecular and intramolecular kinetic isotope effects (KIE) for some ene reactions of hetero enophiles

1986 ◽  
Vol 51 (1) ◽  
pp. 37-40 ◽  
Author(s):  
Walter Starflinger ◽  
Guenter Kresze ◽  
Keith Huss
Keyword(s):  
Reaction Mechanisms ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Ene Reactions ◽  
Ene Reaction ◽  
Kinetic Isotope

Mechanism of the dimethyl mesoxalate-alkene ene reaction. Deuterium kinetic isotope effects

1980 ◽  
Vol 45 (23) ◽  
pp. 4774-4776 ◽  
Author(s):  
Osman Achmatowicz ◽  
Jan Szymoniak
Keyword(s):  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Ene Reaction ◽  
Kinetic Isotope

Intramolecular and Intermolecular Kinetic Isotope Effects (KIE) in the Nitrosoarene Ene Reaction:  Experimental Evidence for Reversible Intermediate Formation

2003 ◽  
Vol 68 (6) ◽  
pp. 2420-2425 ◽  
Author(s):  
Waldemar Adam ◽  
Oliver Krebs ◽  
Michael Orfanopoulos ◽  
Manolis Stratakis ◽  
Georgios C. Vougioukalakis
Keyword(s):  
Experimental Evidence ◽  
Isotope Effects ◽  
Intermediate Formation ◽  
Kinetic Isotope Effects ◽  
Ene Reaction ◽  
Kinetic Isotope

Kinetic Isotope Effects and rganic Reaction Mechanisms

Science ◽  
1966 ◽  
Vol 154 (3757) ◽  
pp. 1616-1621 ◽  
Author(s):  
M. J. Goldstein
Keyword(s):  
Reaction Mechanisms ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope

scholarly journals How coverage influences thermodynamic and kinetic isotope effects for H2/D2 dissociative adsorption on transition metals

2020 ◽  
Vol 10 (3) ◽  
pp. 671-689 ◽  
Author(s):  
Benjamin W. J. Chen ◽  
Manos Mavrikakis
Keyword(s):  
Transition Metals ◽  
Reaction Mechanisms ◽  
Hydrogen Isotope ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Dissociative Adsorption ◽  
Kinetic Isotope

Hydrogen isotope effects are influenced by adsorbate coverage: at high coverages, isotope effects are lower than at low coverages. This helps to rationalize observed isotope effects, allowing more precise elucidation of reaction mechanisms.

ChemInform Abstract: Kinetic Isotope Effects in the Study of Organometallic Reaction Mechanisms

ChemInform ◽  
2011 ◽  
Vol 42 (47) ◽  
pp. no-no
Author(s):  
Mar Gomez-Gallego ◽  
Miguel A. Sierra
Keyword(s):  
Reaction Mechanisms ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope

Allene-perfluorocycyclobutanone ene reaction. Kinetic isotope effects

1972 ◽  
Vol 94 (11) ◽  
pp. 3953-3954 ◽  
Author(s):  
Sheng-Hong Dai ◽  
William R. Dolbier
Keyword(s):  
Reaction Kinetic ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Ene Reaction ◽  
Kinetic Isotope

Reaction branching and extreme kinetic isotope effects in the study of reaction mechanisms

1989 ◽  
Vol 18 ◽  
pp. 209 ◽  
Author(s):  
Alf Thibblin ◽  
Per Ahlberg
Keyword(s):  
Reaction Mechanisms ◽  
Isotope Effects ◽  
Kinetic Isotope Effects ◽  
Kinetic Isotope
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