Seeing single silicon atom vibrations

Science ◽  
2020 ◽  
Vol 367 (6482) ◽  
pp. 1086.18-1088
Author(s):  
Phil Szuromi
Keyword(s):  
Silicon Atom

Clusterization Effect on the 29Si NMR Signal of a Spiro Silicon Atom

2021 ◽  
Author(s):  
Akihiro Tsurusaki ◽  
Hiroyasu Sato ◽  
Soichiro Kyushin
Keyword(s):  
Silicon Atom ◽  
29Si Nmr

scholarly journals In silico search for planar hexacoordinate silicon atom: A kinetically viable species

2021 ◽  
Author(s):  
Amlan J. Kalita ◽  
Shahnaz S. Rohman ◽  
Chayanika Kashyap ◽  
Sabnam S. Ullah ◽  
Indrani Baruah ◽  
...  
Keyword(s):  
Silicon Atom ◽  
In Silico

Phosphine-Stabilized Germasilenylidene: Source for a Silicon-Atom Transfer

2021 ◽  
Author(s):  
Christian Wilhelm ◽  
Dominik Raiser ◽  
Hartmut Schubert ◽  
Christian P. Sindlinger ◽  
Lars Wesemann
Keyword(s):  
Silicon Atom ◽  
Atom Transfer

The synthesis and polymerization of vinyl silanes possessing two functional groups on the silicon atom

1977 ◽  
Vol 19 (4) ◽  
pp. 868-874 ◽  
Author(s):  
K.A. Andrianov ◽  
N.V. Delazari ◽  
N.A. Yemel'kina ◽  
Z.V. Pechorkina ◽  
L.A. Leites
Keyword(s):  
Functional Groups ◽  
Silicon Atom ◽  
Vinyl Silanes

Pentacoordination of the silicon atom in phenacetoxymethyltrifluorosilane

1986 ◽  
Vol 35 (12) ◽  
pp. 2486-2489
Author(s):  
G. A. Gavrilova ◽  
N. N. Chipanina ◽  
Yu. L. Frolov ◽  
B. Shirchin ◽  
M. G. Voronkov
Keyword(s):  
Silicon Atom

ChemInform Abstract: Reversible Intramolecular Base-Stabilization of the Low-Coordinate Silicon Atom in the Silanediyl Complex ((o-Me2NCH2C6H4)2Si=Cr(CO)5).

ChemInform ◽  
2010 ◽  
Vol 22 (44) ◽  
pp. no-no
Author(s):  
R. PROBST ◽  
C. LEIS ◽  
S. GAMPER ◽  
E. HERDTWECK ◽  
C. ZYBILL ◽  
...  
Keyword(s):  
Silicon Atom

Two fold coordinated silicon atom: a hole trap in SiO2

2002 ◽  
Vol 121 (6-7) ◽  
pp. 301-304 ◽  
Author(s):  
V.A. Gritsenko ◽  
A.V. Shaposhnikov ◽  
G.M. Zhidomirov ◽  
M. Roger
Keyword(s):  
Silicon Atom ◽  
Hole Trap

scholarly journals Preparation of optically active bicyclodihydrosiloles by a radical cascade reaction

2013 ◽  
Vol 9 ◽  
pp. 1326-1332 ◽  
Author(s):  
Koichiro Miyazaki ◽  
Yu Yamane ◽  
Ryuichiro Yo ◽  
Hidemitsu Uno ◽  
Akio Kamimura
Keyword(s):  
Silicon Atom ◽  
Cascade Reaction ◽  
Radical Cyclization ◽  
Optically Active ◽  
Unsaturated Ester ◽  
Terminal Alkyne ◽  
Silyl Radical ◽  
Vinyl Radical ◽  
Radical Cascade ◽  
Carbonyl Radical

Bicyclodihydrosiloles were readily prepared from optically active enyne compounds by a radical cascade reaction triggered by tris(trimethylsilyl)silane ((Me3Si)3SiH). The reaction was initiated by the addition of a silyl radical to an α,β-unsaturated ester, forming an α-carbonyl radical that underwent radical cyclization to a terminal alkyne unit. The resulting vinyl radical attacked the silicon atom in an SHi manner to give dihydrosilole. The reaction preferentially formed trans isomers of bicyclosiloles with an approximately 7:3 to 9:1 selectivity.

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