Mass spectrometric method of field evaporation of ions from solutions as a potential possibility of the experimental determination of changes in the enthalpy of solvation of ions and ion clusters in electrolyte solutions

2007 ◽  
Vol 416 (2) ◽  
pp. 275-279 ◽  
Author(s):  
N. B. Zolotoy ◽  
G. V. Karpov
2017 ◽  
Author(s):  
Xueming Dong

Catalytic deoxygenation of coal enhances the stability and combustion performance of coal-derived liquids. However, determination of the selectivity of removal of oxygen atoms incorporated in or residing outside of aromatic rings is challenging. This limits the ability to evaluate the success of catalytic deoxygenation processes. A mass spectrometric method, in-source collision-activated dissociation (ISCAD), combined with high resolution product ion detection, is demonstrated to allow the determination of whether the oxygen atoms in aromatic compounds reside outside of aromatic rings or are part of the aromatic system, because alkyl chains can be removed from aromatic cores via ISCAD. Application of this method for the analysis of a subbituminous coal treated using a supported catalyst revealed that the catalytic treatment reduced the number of oxygen-containing heteroaromatic rings but not the number of oxygen atoms residing outside the aromatic rings.<br>


2017 ◽  
Author(s):  
Xueming Dong

Catalytic deoxygenation of coal enhances the stability and combustion performance of coal-derived liquids. However, determination of the selectivity of removal of oxygen atoms incorporated in or residing outside of aromatic rings is challenging. This limits the ability to evaluate the success of catalytic deoxygenation processes. A mass spectrometric method, in-source collision-activated dissociation (ISCAD), combined with high resolution product ion detection, is demonstrated to allow the determination of whether the oxygen atoms in aromatic compounds reside outside of aromatic rings or are part of the aromatic system, because alkyl chains can be removed from aromatic cores via ISCAD. Application of this method for the analysis of a subbituminous coal treated using a supported catalyst revealed that the catalytic treatment reduced the number of oxygen-containing heteroaromatic rings but not the number of oxygen atoms residing outside the aromatic rings.<br>


2017 ◽  
Vol 280 ◽  
pp. S292
Author(s):  
Gordana Brajković ◽  
Jasmina Jović-Stošić ◽  
Snežana Đorđević ◽  
Vesna Kilibarda ◽  
Marijana Čurćić ◽  
...  

Amino Acids ◽  
2021 ◽  
Author(s):  
Duygu Eryavuz Onmaz ◽  
Kevser Isik ◽  
Abdullah Sivrikaya ◽  
Sedat Abusoglu ◽  
İlknur Albayrak Gezer ◽  
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