Thermal properties of ternary systems: The calculation of the standard enthalpy of solution for compounds in binary mixtures

Enthalpies of solution of LiCl, NaCl, (CH3) 4NBr, (C2H5)4 NBr, (C3H7)4 NBr, and (C4H9)4 NBr in dioxane-water mixtures varying in composition from 20 to 64.5% dioxane have been determined. Values of standard enthalpy of solution, ΔHs0, were obtained using the extended Debye–Hückel equation.Using these ΔHs0 and the lattice energies (U) of these salts, solvation enthalpies have been evaluated.

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The standard enthalpy of solution of NH4NO3(c, IV) in water at 298.15 K. (A search for the standard thermodynamic state.)

The Journal of Chemical Thermodynamics ◽

10.1016/0021-9614(80)90112-3 ◽

1980 ◽

Vol 12 (1) ◽

pp. 27-40 ◽

Cited By ~ 25

Author(s):

C.E Vanderzee ◽

Dan H Wauch ◽

Norman C Haas ◽

Dwight A Wigg

Keyword(s):

Standard Enthalpy ◽

Enthalpy Of Solution ◽

Thermodynamic State ◽

Standard Enthalpy Of Solution

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Standard Enthalpy of Solution of Crystalline DL-Alanyl-DL-Norvaline

Russian Journal of Physical Chemistry A ◽

10.1134/s0036024419020171 ◽

2019 ◽

Vol 93 (2) ◽

pp. 271-274

Author(s):

A. I. Lytkin ◽

V. V. Chernikov ◽

O. N. Krutova ◽

V. G. Badelin ◽

G. N. Tarasova

Keyword(s):

Standard Enthalpy ◽

Enthalpy Of Solution ◽

Standard Enthalpy Of Solution

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Standard enthalpy of solution and formation of cesium chromate. Derived thermodynamic properties of the aqueous chromate, bichromate, and dichromate ions, alkali metal and alkaline earth chromates, and lead chromate

The Journal of Chemical Thermodynamics ◽

10.1016/0021-9614(75)90042-7 ◽

1975 ◽

Vol 7 (12) ◽

pp. 1195-1204 ◽

Cited By ~ 29

Author(s):

P.A.G. O'Hare ◽

Juliana Boerio

Keyword(s):

Thermodynamic Properties ◽

Alkali Metal ◽

Standard Enthalpy ◽

Alkaline Earth ◽

Enthalpy Of Solution ◽

Lead Chromate ◽

Standard Enthalpy Of Solution ◽

Dichromate Ions

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Catalytic hydrogenation of binary and ternary mixtures of unsaturated substances in the liquid phase on platinum

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19792378 ◽

1979 ◽

Vol 44 (8) ◽

pp. 2378-2383 ◽

Cited By ~ 9

Author(s):

Libor Červený ◽

Radka Junová ◽

Vlastimil Růžička

Keyword(s):

Liquid Phase ◽

Binary Mixtures ◽

Silica Gel ◽

Catalytic Hydrogenation ◽

Ternary Systems ◽

Ternary Mixtures ◽

Unsaturated Alcohol ◽

Solvent Concentration ◽

Binary And Ternary Mixtures ◽

Hydrogenation Selectivity

Hydrogenation of olefinic substrates in binary and ternary mixtures using 5% Pt on silica gel as the catalyst was studied in normal conditions in the liquid phase with methanol or cyclohexane or in solvent-free systems. The effect of the solvent concentration on the selectivity of hydrogenation of the unsaturated alcohol-olefin binary mixtures was investigated. In ternary systems of unsaturated substrates, the effect of each of the substrates on the selectivity of hydrogenation of the remaining two substances was examined. Another system was found in which a jump change of the hydrogenation selectivity occurred on the vanishing of the fastest reacting substance.

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