Oxidation of Porous HfB2–SiC Ultra-High-Temperature Ceramic Materials Rich in Silicon Carbide (65 vol %) by a Supersonic Air Flow

2020 ◽  
Vol 65 (4) ◽  
pp. 606-615 ◽  
Author(s):  
E. P. Simonenko ◽  
N. P. Simonenko ◽  
A. N. Gordeev ◽  
A. F. Kolesnikov ◽  
A. S. Lysenkov ◽  
...  
2019 ◽  
Vol 64 (14) ◽  
pp. 1849-1853 ◽  
Author(s):  
E. P. Simonenko ◽  
N. P. Simonenko ◽  
A. S. Mokrushin ◽  
V. G. Sevastyanov ◽  
N. T. Kuznetsov

2021 ◽  
Vol 87 (8) ◽  
pp. 51-63
Author(s):  
A. M. Shestakov

An increase the operating temperature range of structural elements and aircraft assemblies is one of the main goals in developing advanced and new models of aerospace equipment to improve their technical characteristics. The most heat-loaded aircraft structures, such as a combustion chamber, high-pressure turbine segments, nozzle flaps with a controlled thrust vector, must have a long service life under conditions of high temperatures, an oxidizing environment, fuel combustion products, and variable mechanical and thermal loads. At the same time, modern Ti and Ni-based superalloys have reached the limits of their operating temperatures. The leading world aircraft manufacturers — General Electric (USA), Rolls-Royce High Temperature Composite Inc. (USA), Snecma Propulsion Solide (France) — actively conduct fundamental research in developing ceramic materials with high (1300 – 1600°C) and ultrahigh (2000 – 2500°C) operating temperatures. However, ceramic materials have a number of shortcomings attributed to the high brittleness and low crack resistance of monolithic ceramics. Moreover, manufacturing of complex configuration and large-sized ceramic parts faces serious difficulties. Nowadays, ceramic composite materials with a high-temperature matrix (e.g., based on ZrC-SiC) and reinforcing filler, an inorganic fiber, (e.g., silicon carbide) appeared most promising for operating temperatures above 1200°C and exhibited enhanced energy efficiency. Ceramic fibers based on silicon compounds possess excellent mechanical properties: the tensile strength more than 2 GPa, modulus of elasticity more than 200 GPa, and thermal resistance at a temperature above 800°C, thus making them an essential reinforcing component in metal and ceramic composites. This review is devoted to silicon carbide core fibers obtained by chemical vapor deposition of silicon carbide onto a tungsten or carbon core, which makes it possible to obtain fibers a 100 – 150 μm in diameter to be used in composites with a metal matrix. The coreless SiC-fibers with a diameter of 10 – 20 μm obtained by molding a polymer precursor from a melt and used mainly in ceramic composites are also considered. A comparative analysis of the phase composition, physical and mechanical properties and thermal-oxidative resistance of fibers obtained by different methods is presented. Whiskers (filamentary crystals) are also considered as reinforcing fillers for composite materials along with their properties and methods of production. The prospects of using different fibers and whiskers as reinforcing fillers for composites are discussed.


2020 ◽  
Vol 40 (4) ◽  
pp. 1093-1102 ◽  
Author(s):  
Elizaveta P. Simonenko ◽  
Nikolay P. Simonenko ◽  
Andrey N. Gordeev ◽  
Anatoly F. Kolesnikov ◽  
Anton S. Lysenkov ◽  
...  

2013 ◽  
Vol 58 (14) ◽  
pp. 1669-1693 ◽  
Author(s):  
E. P. Simonenko ◽  
D. V. Sevast’yanov ◽  
N. P. Simonenko ◽  
V. G. Sevast’yanov ◽  
N. T. Kuznetsov

Author(s):  
Vasiliy Kovbashyn ◽  
Igor Bochar

The study describes the properties of the protective coating deposited on the surface of the reaction-sintered silicon carbide and molybdenum disilicide. The technology of increasing the protective ability of the coating of products deposited on the surface on the basis of reactive sintered carbide of silicon and molybdenum disilicide, which operate in an oxidizing environment at high temperature and a sharp change of thermal regime, is investigated. The obtained results showed that the presence of a protective slip layer significantly increases the stability of the deposited silicoboride coating, thus blocking the interaction of silicon hexaboride with the environment, slowing down almost all diffusion processes at the transition of the interaction of diffusion. It has been established that the simultaneous use of both diffusion and slurry coatings enables maximum protection of reaction-sintered ceramic materials based on silicon carbide and molybdenum disilicide against high-temperature gas corrosion. The developed coating ensures maximum resistance to repeated changes in temperature conditions, while cyclic changes destroy products of silicon carbide and molybdenum disilicide without applied protective coating. The proposed protective coating can be recommended for the protection of reaction-sintered ceramic materials operated in high temperatures.


2007 ◽  
Vol 16 (4) ◽  
pp. 30-36 ◽  
Author(s):  
Eric Wuchina ◽  
Elizabeth Opila ◽  
Mark Opeka ◽  
Bill Fahrenholtz ◽  
Inna Talmy

1991 ◽  
Vol 250 ◽  
Author(s):  
Lisa C. Veitch ◽  
Francis M. Terepka ◽  
Suleyman A. Gokoglu

AbstractStructural fibers are currently being considered as reinforcements for intermetallic and ceramic materials. Some of these fibers, however, are easily degraded in a high temperature oxidative environment. Therefore, coatings are needed to protect the fibers from environmental attack.Silicon carbide (SiC) was chemically vapor deposited (CVD) on Textron's SCS6 fibers. Fiber temperatures ranging from 1350 to 1500 °C were studied. Silane (SiH4) and propane (C3H8.) were used for the source gases and different concentrations of these source gases were studied. Deposition rates were determined for each group of fibers at different temperatures. Less variation in deposition rates were observed for the dilute source gas experiments than the concentrated source gas experiments. A careful analysis was performed on the stoichiometry of the CVD SiC-coating using electron microprobe. Microstructures for the different conditions were compared. At 1350°C, the microstructures were similar;however, at higher temperatures, the microstructure for the more concentrated source gas group were porous and columnar in comparison to the cross sections taken from the same area for the dilute source gas group.


2015 ◽  
Vol 820 ◽  
pp. 250-255 ◽  
Author(s):  
Mariah Oliveira Juliani ◽  
Carolyne Davi Oliveria ◽  
Rosa Maria Rocha

Zirconium diboride (ZrB2) is a covalent compound that leads the category of ultra high temperature ceramics materials owing to its unique properties. In this work, the effect of addition of beta-silicon carbide (β-SiC) in pressureless sintering of ZrB2 was investigated. Four compositions were prepared with 0, 10, 20 e 30 vol% of SiC. ZrB2 powder and mixtures were prepared in by planetary milling with SiC spheres at 4 h. Two sintering temperatures were used, one at 2050 oC/1h and other at 2150 °C/1h. The addition of SiC has promoted an increasing in densification with the increasing of SiC content. The total densification of sample sintered at 2050 oC was 90% of theoretical density for sample with 30 vol% of SiC, while the maximum densification for temperature of 2150 oC was 91,0 %TD.


2008 ◽  
Vol 28 (9) ◽  
pp. 1899-1907 ◽  
Author(s):  
Raffaele Savino ◽  
Mario De Stefano Fumo ◽  
Laura Silvestroni ◽  
Diletta Sciti

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