Electrochemical Synthesis, Properties, and Structure of 1,10-Phenanthroline Adducts of Mononuclear Copper, Cobalt, and Nickel Chelates in the N,N,O-Ligand Environment

2018 ◽  
Vol 44 (10) ◽  
pp. 596-603 ◽  
Author(s):  
D. A. Garnovskii ◽  
V. G. Vlasenko ◽  
G. G. Aleksandrov ◽  
S. I. Levchenkov ◽  
N. I. Makarova ◽  
...  
Keyword(s):  
Electrochemical Synthesis ◽  
Ligand Environment ◽  
Nickel Chelates ◽  
Synthesis Properties ◽  
Cobalt And Nickel

The direct electrochemical synthesis of thiolato complexes of cobalt and nickel, and the crystal structure of bis(phenylthiolato)bis(1,10-phenanthroline)cobalt(III) perchlorate

1988 ◽  
Vol 66 (9) ◽  
pp. 2151-2156 ◽  
Author(s):  
Raj K. Chadha ◽  
Rajesh Kumar ◽  
Jaime Romero Lopez-Grado ◽  
Dennis G. Tuck
Keyword(s):  
Crystal Structure ◽  
Electrochemical Oxidation ◽  
Electrochemical Synthesis ◽  
Crystallographic Analysis ◽  
High Yield ◽  
X Ray ◽  
Metal Anode ◽  
Aerial Oxidation ◽  
Perchlorate Salt ◽  
Cobalt And Nickel

Cobalt(II) and nickel(II) thiolates, M(SR)2, can be prepared in high yield by the electrochemical oxidation of a metal anode in an acetonitrile or acetone solution of RSH (R = C6H5, o-CH3C6H4, 2-C10H7, 2,3,4,5-C6F4H; not all combinations). When 2,2-bipyridine or 1,10-phenanthroline (=L) is added to the electrolyte phase, the products are the adducts M(SR)2L2. In the case of Co(SC6H5)2(phen)2, aerial oxidation leads to the formation of the cobalt(III) cation [Co(SC6H5)2(phen)2]+, isolated as the perchlorate salt. X-ray crystallographic analysis showed that this cation has a cis-CoS2(N2)2 kernel.

Elektrochemische Synthesen, V Phosphansubstituierte Metallcarbonyle der Eisengruppe/ Electrochemical Syntheses, V Phosphane Substituted Metal Carbonyls of the Iron Group Elements

1981 ◽  
Vol 36 (1) ◽  
pp. 8-13 ◽  
Author(s):  
Joseph Grobe ◽  
Bernd Heinz Schneider
Keyword(s):  
Electrochemical Synthesis ◽  
Iron Group ◽  
Metal Carbonyls ◽  
Iron Cobalt ◽  
Nickel Carbonyl ◽  
Carbonyl Derivatives ◽  
Cobalt And Nickel ◽  
Metal Anodes

Abstract The electrochemical synthesis of iron, cobalt, and nickel carbonyl derivatives with phosphane ligands from metal anodes is described.

Electrochemical synthesis, properties, and structure of copper, nickel, and cobalt complexes of tridentate tosylamino-functionalized mercaptopyrazole Schiff base

2017 ◽  
Vol 43 (3) ◽  
pp. 156-163 ◽  
Author(s):  
D. A. Garnovskii ◽  
S. I. Levchenkov ◽  
G. G. Aleksandrov ◽  
V. G. Vlasenko ◽  
Ya. V. Zubavichus ◽  
...  
Keyword(s):  
Schiff Base ◽  
Electrochemical Synthesis ◽  
Cobalt Complexes ◽  
Copper Nickel ◽  
Synthesis Properties

Electrochemical synthesis and structure of 2-amino-1-ethylbenzimidazole adducts of copper, cobalt, and zinc chelates in the N,N,S ligand environment

2017 ◽  
Vol 62 (8) ◽  
pp. 1077-1084 ◽  
Author(s):  
D. A. Garnovskii ◽  
G. G. Aleksandrov ◽  
N. I. Makarova ◽  
S. I. Levchenkov ◽  
V. G. Vlasenko ◽  
...  
Keyword(s):  
Electrochemical Synthesis ◽  
Ligand Environment

Synthesis, Properties, and Antimicrobial Activity of Pectin Complexes with Cobalt and Nickel

2016 ◽  
Vol 52 (1) ◽  
pp. 26-31 ◽  
Author(s):  
S. T. Minzanova ◽  
V. F. Mironov ◽  
L. G. Mironova ◽  
I. R. Nizameev ◽  
K. V. Kholin ◽  
...  
Keyword(s):  
Antimicrobial Activity ◽  
Synthesis Properties ◽  
Cobalt And Nickel

Elektrochemische Synthesen, IV Metallcarbonylverbindungen der Eisengruppe/Electrochemical Syntheses, IV Metal Carbonyl Compounds of the Iron Group Elements

1981 ◽  
Vol 36 (1) ◽  
pp. 1-7 ◽  
Author(s):  
Joseph Grobe ◽  
Bernd Heinz Schneider
Keyword(s):  
Solvent Effects ◽  
Electrochemical Synthesis ◽  
Carbonyl Compounds ◽  
Cluster Formation ◽  
Metal Carbonyl ◽  
Iron Group ◽  
Metal Acetylacetonates ◽  
Iron Cobalt ◽  
Nickel Carbonyl ◽  
Cobalt And Nickel

Abstract The electrochemical synthesis of iron, cobalt, and nickel carbonyl compounds from metal acetylacetonates of oxidation state + II or + III and from metal anodes is described, solvent effects and the problem of cluster formation are discussed.

Direct electrochemical synthesis and characterization of cobalt and nickel complexes with 2-pyridinone and 2-pyridinemethanethiol-1-oxide

1994 ◽  
Vol 19 (2) ◽  
pp. 209-211 ◽  
Author(s):  
Jesus Sanmartín ◽  
Manuel R. Bermejo ◽  
José A. García-Vázquez ◽  
Jaime Romero ◽  
Antonio Sousa
Keyword(s):  
Electrochemical Synthesis ◽  
Nickel Complexes ◽  
Synthesis And Characterization ◽  
Cobalt And Nickel
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