The crystal structure of nickel(II) dimethyldithiocarbamate
1980 ◽
Vol 45
(8)
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pp. 2147-2151
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Keyword(s):
X Ray
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Crystal and molecular structure of nickel(II) dimethyldithiocarbamate, Ni[S2CN(CH3)2]2 was solved by X-ray structural analysis and refined by the least squares method to R = 0.06 for 1065 reflections. The compound crystallizes in a space group P I and the triclinic unit cell has the dimensions: a = 6.521 (7), b = 6.798 (9), c = 7.633 (4), α = 67.21 (8)°, β = 67.34 (6)° γ =85.59 (9)°. The experimentally observed density is 1.75 g cm-3 and the calculated value for Z = 1 is 1.73 g cm-3. In the structure , the Ni atom occupies a special position in the centre of symmetry and is coordinated by four sulphur atoms in a plane: Ni-S 0.2218 (4) and 0.2198 nm S1-Ni-S2 angle 79.62 (8)°. The ligand S2CNC2 is nearly planar.
1982 ◽
Vol 47
(10)
◽
pp. 2633-2638
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The crystal and molecular structure of tris-butyl-tin(IV)-(1-pyrrolidinecarbodithioato)-3-propionate
1989 ◽
Vol 54
(3)
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pp. 684-690
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1982 ◽
Vol 47
(10)
◽
pp. 2623-2632
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1984 ◽
Vol 49
(10)
◽
pp. 2363-2370
1986 ◽
Vol 51
(11)
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pp. 2521-2527
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1975 ◽
Vol 30
(1-2)
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pp. 14-18
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