The Diels-Alder reaction of butadiene with hexacyclic olefins in the synthesis of triamantane
1986 ◽
Vol 51
(5)
◽
pp. 1083-1085
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Keyword(s):
The paper describes the composition of products arising from the Diels-Alder reaction of butadiene with hexacyclic olefins (hexacyclo[8,4,0,02,7,03,14,04,8,09,13]tetradec-5-ene and hexacyclo[6,6,0,02,6,05,14,07,12,09,13]tetradec-3-ene) under different conditions. The reaction afforded a mixture of heptacyclic olefins (heptacyclo[8,8,0,02,17,03,11,04,9,012,16,013,18]octadec-6-ene and heptacyclo[8,8,0,02,13,03,11,04,9,012,17,014,18]octadec-6-ene), which is an important intermediate in the synthesis of triamantane.
2020 ◽
2016 ◽
Vol 20
(22)
◽
pp. 2421-2442
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2014 ◽
Vol 18
(12)
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pp. 1586-1620
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2018 ◽
Vol 15
(2)
◽
pp. 221-229
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2008 ◽
Vol 73
(12)
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pp. 1764-1776
Keyword(s):
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