Structure of the Tris(diallyldithiocarbamate)cobalt(III) Complex
1992 ◽
Vol 57
(2)
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pp. 332-338
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Keyword(s):
The structure of [Co{S2CN(CH2-CH=CH2)2}3] was determined by the heavy atom method, all nonhydrogen atoms being refined by anisotropic diagonal approximation using the least squares method to the value of R= 0.067 for 1 024 reflections with I ≥ 1.96σ(I). The substance is isostructural with [Fe{S2CN(CH2-CH=CH2)2}3], crystallizes in the monoclinic system, space group C2/c, lattice parameters a = 1.8763(9), b = 1.0209(5), c = 1.5402(7) nm, β = 106.18(4)°, Z = 4. Cobalt is coordinated by 3 dithiocarbamate ligands in the bidentate way, the average Co-S lenght is 0.2267(2) nm. The metal atom and two ligand atoms are located on the twofold axis. The CoS6 polyhedron is a trigonally distorted octahedron.
1975 ◽
Vol 53
(15)
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pp. 2345-2350
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Keyword(s):
1989 ◽
Vol 54
(9)
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pp. 2408-2414
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1992 ◽
Vol 57
(11)
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pp. 2309-2314
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Keyword(s):
1977 ◽
Vol 146
(4-6)
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Keyword(s):
1986 ◽
Vol 51
(11)
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pp. 2521-2527
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1980 ◽
Vol 43
(330)
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pp. 753-759
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1973 ◽
Vol 51
(18)
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pp. 3027-3031
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Keyword(s):
1981 ◽
Vol 59
(18)
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pp. 2746-2749
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Keyword(s):